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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 21, Number 5
BKCSDE 21(5)
May 20, 2000 

Rotational Distribution of CO2(OOoO)after Collisions with Hot Atoms
Yoo Hang Kim
By use of the rotational distribution expression previously derived based on the collisional time correlation function formalism, the rotational distributions of CO2 vibrational ground state (OO˚O) after collisions with hot H, D, or Cl atom have been constructed. Energy and rotational quantum number parameters which can characterize the rotational distributions are also calculated and compared with those deduced from the experimental distribution. The results from this work would be very useful in predicting the rotational distributions in the lower J region for which experimental data are not available due to the interference from the ambient CO₂.
493 - 496
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