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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 23, Number 3
BKCSDE 23(3)
March 20, 2002 

Iron(II) Tris(3-bromo-1,10-phenanthroline) Complex: Synthesis, Crystal Structure and Electropolymerization
Kyeong Jong Lee, Il Yoon, Shim Sung Lee, Bu Yong Lee
Electropolymerization, Poly-[Fe(3-Br-phen)3]2+, Glassy carbon disk electrode, X-Ray crystal structure, Absorption spectroscopy.
The complex of iron(Ⅱ) tris(3-Br-phen) (3-Br-phen; 3-bromo-1,10-phenanthroline) was prepared as a precursor of electropolymerization and the crystal structure of [Fe(3-Br-phen)3](PF6)2·CH3CN with a distorted octahedral geometry has been investigated. The reductive electropolymerization of [Fe(3-Br-phen)3]2+ complex onto the surface of a glassy carbon electrode and indium tin oxide (ITO) optically transparent electrode were performed in acetonitrile at room temperature. Thin film of poly-[Fe(3-Br-phen)3]2+ formed was adherent, electroactive and stably deposited on a glassy carbon disk electrode. The thin metallopolymeric film formed was also confirmed by absorption spectroscopy.
399 - 403
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