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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 23, Number 3
BKCSDE 23(3)
March 20, 2002 

 
Title
Diozonides from Coozonolyses of Cyclodienes and Carbonyl Compounds
Author
Shin Hee Park, Tae Sung Huh
Keywords
Diozonides, Coozonolyses, Cyclodienes.
Abstract
Treatment of conjugated cyclodienes (5a-5c) with excess ozone in dichoromethane in the presence of added carbonyl compounds (3) resulted to give the corresponding diozonides 10 and cross-ozonides 14. Similarly, ozonolysis of the nonconjugated 1,4-cyclohexadiene (6a) and 1,5-cyclooctadiene (6b) under same conditions afforded both diozonides 20 and cross-ozonides 14. On the other hand, Ozonolysis of bicyclo[2.2.0]hepta-2,5-diene (6c) in the presence of 3A provided the corresponding diozonide 19.
Page
423 - 426
Full Text
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