Current time in Korea 01:58 Oct 19 (Thu) Year 2017 KCS KCS Publications
KCS Publications
My Journal Log In Register
HOME > Search > Browsing(BKCS) > Archives

Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 23, Number 5
BKCSDE 23(5)
May 20, 2002 

 
Title
Partial Oxidation of Methane over Ni/SiO2
Author
Hyun-Seog Roh, Wen-Sheng Dong, Ki-Won Jun, Zhong-Wen Liu, Sang-Eon Park, Young-Sam Oh
Keywords
Methane, Ni/SiO2, POM, Pulse reaction, Reforming.
Abstract
Ni catalyst (Ni: 15 wt%) supported on precalcined SiO2 has been investigated in reforming reactions of methane to synthesis gas. The catalyst exhibited fairly good activity and stability in partial oxidation of methane (POM), whereas it deactivated in steam reforming of methane (SRM). Pulse reaction results of CH4, O2, and CH4/O2 revealed that Ni/SiO2 has high capability to dissociate methane. The results also revealed that both CH4 and O2 are activated on the surface of metallic Ni, and then surface carbon species react with adsorbed oxygen to produce CO and CO2 depending on the bond strength of the oxygen species on the catalyst surface.
Page
669 - 673
Full Text
PDF