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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 23, Number 9
BKCSDE 23(9)
September 20, 2002 

 
Title
A Facile One-Pot Operations of Reduction and Allylation of Nitrobenzaldehydes Mediated by Indium and Their Applications
Author
Yong Seo Cho, Kyung Ho Kang, Joo Hwan Cha, Kyung Il Choi, Ae Nim Pae, Hun Yeong Koh, Moon Ho Chang
Keywords
Simultaneous reduction-allylation, Indium, Aqueous media
Abstract
Various nitrobenzaldehydes were simultaneously allylated and reduced using indium in the presence of HCl in aqueous media to give compounds having both functionality of homoallylic alcohol and aromatic amine. Sequential protection of the amino group and oxidation of the anilinyl homoallylic alcohol provided useful precursors of heterocyclic compounds such as dihydroindolones and dihydroquinolones, which could be efficiently synthesized through intramolecular cyclization reaction.
Page
1285 - 1290
Full Text
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