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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 23, Number 11
BKCSDE 23(11)
November 20, 2002 

 
Title
Halogenated Cleavage of Epoxides into Halohydrins in the Presence of a Series of Diamine Podands as Catalyst with Elemental Iodine and Bromine
Author
Hashem Sharghi, Zahra Paziraee, Khodabakhsh Niknam
Keywords
Vesicle, Polymerizable surfactant, Skeletonization, Hydrolysis
Abstract
The ring opening of epoxides with elemental iodine and bromine in the presence of three diamine podands 7-9 as new catalysts affords vicinal iodo alcohols and bromo alcohols in high yields. This new procedure occurs regioselectively under neutral and mild conditions in various aprotic solvents even when sensitive functional groups are presented.
Page
1611 - 1615
Full Text
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