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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 24, Number 5
BKCSDE 24(5)
May 20, 2003 

 
Title
Sorbent Extraction of Some Metal Ions on a Gas Chromatographic Stationary Phase Prior to Their Flame Atomic Absorption Determinations
Author
M. Soylak, S. Saracoglu, L. Elci
Keywords
Trace metals, Impurities, Chromosorb-102, Preconcentration, Calmagite
Abstract
An enrichment/separation system for atomic absorption spectrometric determinations of Cu(II), Fe(III), Ni(II) and Co(II) has been established. The procedure is based on the adsorption of the analytes as calmagite chelates on Chromosorb-102. The effects of some parameters including pH, amount of ligand, salt matrix, flow rates of sample and eluent solutions were investigated. Under optimized conditions, the relative standard deviation of the combined method of sample treatment, preconcentration and determination with FAAS (N=5) is generally lower than 5%. The limit of detection (3 s) was between 6.0-112.9 mg/L. The results were used for preconcentration of analytes from some sodium and ammonium salt.
Page
555 - 558
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