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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 24, Number 7
BKCSDE 24(7)
July 20, 2003 

 
Title
FDiastereoselective Synthesis of 1,6-Diepicastanospermine from D-Glucono- d-lactone
Author
Ki Chang Jang, Sung Jun Choi, Jin Hyo Kim, Jin Hwan Lee, Byong Won Lee, Ki Hun Park
Keywords
1,6-Diepicastanospermine, Diastereoselective nucleophilic addition, anti-Aminoalcohol, Vinylmagnesium bromide, D-Glucono- d-lactone
Abstract
Homochiral (-)-pipecolaldehyde 6 from D-glucono- d-lactone underwent a highly diastereoselective addition upon treatment with vinylmagnesium bromide. Treatment with vinylmagnesium bromide produced antiaminoalcohol 7a which was easily converted into the synthesis of 1,6-diepicastanospermine 2.
Page
921 - 924
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