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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 25, Number 9
BKCSDE 25(9)
September 20, 2004 

 
Title
A Convenient Synthesis of Optically Active Unhindered Aliphatic Alcohols with High Optical Purity from Non-Racemic β-Hydroxy Sulfides
Author
Byung Tae Cho*, Dong Jun Kim
Keywords
Chiral aliphatic alcohols, Asymmetric reduction, (S)-CBS oxazaborolidine, Chiral β-hydroxy sulfides
Abstract
A general route for the synthesis of optically active unhindered aliphatic alcohols, where the steric demands between two alkyl groups adjacent to the carbinol are similar, with high enantiomeric purity has been developed by sulfoxifation of chiral β-hydroxy sulfides, followed by alkylation and desulfurization.
Page
1385 - 1391
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