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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 27, Number 2
BKCSDE 27(2)
February 20, 2006 

 
Title
SANS Studies on the Formation of PANI Nanoparticles in the Reverse Micelles
Author
Jae-Hyun Sim, Myungwoong Kim, Sangwook Park, Jeong Hwan Bang, Daewon Sohn*
Keywords
SANS, PANI, Nanoparticles, Micelle, Core-shell
Abstract
The formation of polyaniline (PANI) in the reverse micelles of poly(oxyethylene) nonylphenyl ether, (NP5, H(CH2)9Ph(OC2H4)5OH), was investigated by small-angle neutron scattering (SANS). The reverse micellar solution containing initiators in the inner part of reverse micelle was prepared with surfactant (NP5), water, cyclohexane and an initiator (ammonium persulfate (APS)). The core-shell sphere model containing smearing effect reveals that the polymerization occurs on the shell layer of the reverse micelles. Shell thickness averages varied from 48 A to 109 A with increases of monomer concentration.
Page
251 - 254
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