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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 27, Number 4
BKCSDE 27(4)
April 20, 2006 

 
Title
Regulation of Stereoselectivity and Reactivity in the Inter- and Intramolecular Allylic Transfer Reactions
Author
Chan-Mo Yu*, Jinsoup Youn, Hee-Keum Jung
Keywords
Allylation, Asymmetric synthesis, Catalyst, Selectivity, Stereochemistry
Abstract
The preparation of enatiomerically enriched homoallylic alcohols through asymmetric addition of chiral allylic transfer reagents and allylating reagents with chiral catalysts to the carbonyl functionalities represents an important chemical transformation. Excellent progress has been made over past decade in the development and application of catalytic asymmetric allylic transfer reactions. In this account, our efforts for the various intermolecular allylic transfer reactions such as allylation, propargylation, allenylation, and dienylation utilizing accelerating strategy and sequential allylic transfer reactions to achieve multiple stereoselection mainly using transition metal catalysts are described.
Page
463 - 472
Full Text
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