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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 27, Number 4
BKCSDE 27(4)
April 20, 2006 

 
Title
Rh2(Opiv)4-Catalyzed Reactions of Diazo Compound Derived from Meldrum's Acid and Styrenes. Efficient Synthesis of Cyclopropanes
Author
Yong Rok Lee*, Jung Hyun Choi
Keywords
Rh2(Opiv)4-catalyzed reactions, Diazo compound, Cyclopropanes
Abstract
The rhodium(II)-catalyzed reactions of diazo compound derived from Meldrum’s acid with a variety of styrenes have been examined. These reactions provide a rapid route to the preparation of cyclopropanes with a variety of substituents on the benzene ring. The mechanistic pathway for the formation of these products has been also described in terms of a stepwise mechanism.
Page
503 - 507
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