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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 27, Number 8
BKCSDE 27(8)
August 20, 2006 

Novel Two-dimensional Network Based on Amino-acid-octamolybdate Bridged by Second Metals: {M(H2O)3(pro)Mo4O13}2·2H2O (pro = proline, M = Co, Ni, Cu, Zn)
Xiao-Yuan Wu, Can-Zhong Lu*, Chang-Kun Xia, Shu-Mei Chen, Jiu-Hui Liu, Li-Juan Chen, Wen-Bin Yang
Amino acid, Polyoxomolybdate, Hybrid materials, Crystal structure, Magnetism
Four isostructural amino-acid-based polyoxomolybdates, {M(H2O)3(pro)Mo4O13}2·2H2O (pro = proline, M = Co (1), Ni (2), Cu (3), Zn (4)), have been synthesized and structurally characterized by single crystal X-ray diffraction, elemental analysis, IR spectrum, TG analysis. The structures of 1-4 are layered networks built up from {Mo8O26(pro)2}4- units and {M(H2O)3O3} octahedra, the uncoordinated water molecules occupying the interlayer regions.
1206 - 1210
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