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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 28, Number 3
BKCSDE 28(3)
March 20, 2007 

 
Title
Structure of Mixed-Anions Tris(2-pyridylmethyl)amine Mn Complex, TPAMn(η2-NO3)(η-ClO4)
Author
Bok-Kyu Shin, Mihyang Kim, Jaehong Han*
Keywords
Mixed-anions, Seven-coordinated manganese complex, Tripodal ligand, Crystal structure, Nitrate binding
Abstract
Mononuclear mixed-anions Mn complex of TPAMn(η2-NO3)(η-ClO4), where TPA is tris(2-pyridylmethyl)-amine, has been synthesized and characterized. The neutral TPAMn(η2-NO3)(η-ClO4) was obtained from the reaction between Mn(NO3)2·4H2O and [H3TPA](ClO4)3 in MeOH. X-ray crystallographic structure of mononuclear TPAMn(η2-NO3)(η-ClO4) complex showed a seven-coordinated geometry with a tripodal tetradentate TPA, a terminal perchlorate and an η2-bound nitrate.
Page
417 - 420
Full Text
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