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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 28, Number 7
BKCSDE 28(7)
July 20, 2007 

 
Title
Solvent-free Cyanosilylation of Carbonyl Compounds Catalyzed by NbCl5
Author
Soney C. George, Sung Soo Kim*
Keywords
Cyanohydrins, Aldehydes, Ketones, Solvent-free, NbCl5
Abstract
A simple and convenient method for the addition of TMSCN to carbonyl compounds is described. NbCl5 is found to possess a strong Lewis acid property to transform carbonyl compounds smoothly to the corresponding cyanosilylether in high yields (up to 99 %) in solvent- free conditions.
Page
1167 - 0
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