Current time in Korea 12:58 Oct 17 (Tue) Year 2017 KCS KCS Publications
KCS Publications
My Journal Log In Register
HOME > Search > Browsing(BKCS) > Archives

Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 28, Number 11
BKCSDE 28(11)
November 20, 2007 

 
Title
Solvent-free Microwave-Assisted Ortho-Alkylation of Aromatic Ketimine with Acrylic Acid Derivatives by Rh(I) Catalyst
Author
Eun-Ae Jo, Jeong-Ae Ahn, Chul-Ho Jun*
Keywords
ortho-alkylation, Microwave, Rhodium, Homogeneous catalyst, Ketimine
Abstract
Microwave(MW)-assisted ortho-alkylation of aromatic imine with acrylic acid derivatives was performed in the presence of a (PPh3)3RhCl catalyst, and corresponding ortho-alkylated ketones were obtained after hydrolysis of the resulting ketimines. This solventless MW-assisted ortho-alkylation was highly efficient compared with conventional heating, probably due to the specific MW effect.
Page
2020 - 2024
Full Text
PDF