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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 30, Number 4
BKCSDE 30(4)
April 20, 2009 

 
Title
Synthesis and Structure Analysis of α and β Forms of
[12] Metallacrown-6 Nickel(II) Complex: [Ni6(SCH2CH2CH3)12]
Author
Hai Lian Xiao, Fang Fang Jian*, Ke Jie Zhang
Keywords
Polymorphism, Nickel cluster compounds, Crown compounds, Crystal structure
Abstract
Two modifications of the α and β forms of propyl mercaptan nickel(II) cluster, [Ni6(SCH2CH2CH3)12], have been synthesized and their crystal structures have been determined by single-crystal X-ray diffraction. The alkyl groups are away from Ni6 ring in α form whereas they are near to the Ni atom in β form. The distance of Ni-H in β form [2.576(5) A] is much shorter than that in α form [3.101(2) A]. In the crystal lattice of β form, the whole structure forms a flower shape.
Page
846 - 848
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