Current time in Korea 14:52 Oct 17 (Tue) Year 2017 KCS KCS Publications
KCS Publications
My Journal Log In Register
HOME > Search > Browsing(BKCS) > Archives

Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 30, Number 4
BKCSDE 30(4)
April 20, 2009 

 
Title
Decoupling of Background and Resonance Scatterings in Multichannel Quantum Defect Theory and Extraction of Dynamic Parameters from Lu-Fano Plot
Author
Chun Woo Lee
Keywords
MQDT, Resonance, Background scattering, Phase renormalization
Abstract
Giusti-Suzor and Fano introduced translations of the scales of Lu-Fano plots by phase renormalization in order to decouple the intra- and inter-channel couplings in multichannel quantum defect theory (MQDT). Their theory was further developed by others to deal with systems involving a larger number of channels. In different directions, MQDT was reformulated into forms with a one-to-one correspondence to those in Fano's configuration mixing theory of resonance for photofragmentation processes involving one closed and many open channels. In this study, the theory was further developed to fully reveal the coupling nature, decoupling of the background and resonance scattering in physical scattering matrices as well as to further extract the dynamic parameters undiscovered by Fano and his colleagues. This theory was applied to the photoabsorption spectrum of H2 observed by Herzberg's group.
Page
891 - 896
Full Text
PDF