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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 30, Number 10
BKCSDE 30(10)
October 20, 2009 

 
Title
Chemical Equilibria of Nickel Chloride in HCl Solution at 25℃
Author
Man Seung Lee, Sang Ho Nam*
Keywords
NiCl2, HCl, Ionic equilibria, pH
Abstract
Chemical equilbria of nickel chloride in HCl solution at 25 oC were analyzed by considering chemical equilibria, mass and charge balance equations. The activity coefficients of solutes were calculated by using Bromley equation. The necessary thermodynamic properties, such as the equilibrium constant for the formation of NiCl+ at zero ionic strength and interaction parameter, were evaluated by applying Bromley equation to the stability constant data reported in the literature. It was found that most nickel exists as Ni2+ in HCl solution up to 5 molality HCl. The pH values of NiCl2-HCl-H2O system at 25 oC calculated in this study agreed well with the pH values measured by employing pH meter.
Page
2203 - 2207
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