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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 30, Number 12
BKCSDE 30(12)
December 20, 2009 

 
Title
Effect of an Extra Chloro Substituent on Photochemistry of o-Alkylphenacyl Chloride
Author
Bong Ser Park*, Seongjin Jeong
Keywords
Photochemistry, Dichloro ketone, Substituent effect
Abstract
The title compound, α,α-dichloro-o-methylacetophenone, was prepared and its photochemical behavior was investigated. Addition of an extra chlorine at alpha position to the carbonyl showed many different features from photochemical reactivities of mono chloro analogue, 2,5-dimethylphenacyl chloride. In benzene, a rearrangement product with a formal 1,5-Cl shift and a reduction product were formed beside indanone. In methanol, solvolysis and cyclization of a common dienol intermediate occurred at comparable reaction rates.
Page
3053 - 3056
Full Text
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