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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 31, Number 4
BKCSDE 31(4)
April 20, 2010 

 
Title
Synthesis, Characterization and Structure of DBU-hydrobromide-perbromide: A Novel Oxidizing Agent for Selective Oxidation of Alcohols to Carbonyl Compounds
Author
Mehdi Bakavoli*, Mohammad Rahimizadeh, Hossein Eshghi, Ali Shiri, Zahra Ebrahimpour, Reza Takjoo
Keywords
DBU hydrobromide-perbromide, Oxidation, Alcohols
Abstract
A new and efficient reagent for the conversion of primary and secondary alcohols into their corresponding aldehydes and ketones is introduced. The reagent was easily prepared from the reaction of DBU with molecular bromine in CHCl3. The structure of the reagent as DBUH+Br3 ? was determined by single crystal X-ray diffraction analysis.
Page
949 - 952
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