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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 31, Number 6
BKCSDE 31(6)
June 20, 2010 

Multichannel Quantum Defect Study of the Perturber's Effect on the Overlapping Resonances in Rydberg Series for the Systems Involving 2 Closed and Many Open Channels
Chun Woo Lee
Phase-shifted MQDT, Overlapping resonance, 4 Channel QDT
The phase-shifted version of the multichannel quantum-defect theory (MQDT) was reformulated by disentangling the interloper spectrum from the perturbed dense Rydberg series for a systems involving 2 closed and more than 1 open channel. The theory was applied successfully to Martins and Zimmermann's photoionization spectra of the Rydberg series Cu I 3d9 4s(1D2) nd 2G9/2 perturbed by the interloper, 3d9 4p2 4F9/2, for which Cohen's 4 channel QDT had failed. The zero surface graphic of the perturbed Fano's asymmetry parameter q of the autoionization spectrum of dense Rydberg series by the interloper was determined by only two parameters for this system. It was used as a map to trace the transformation route of the 3 channel autoionization spectra to the 4 channel spectra when the channel coupling of the closed channels with a newly added open channel was turned on progressively.
1669 - 1680
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