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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 31, Number 7
BKCSDE 31(7)
July 20, 2010 

 
Title
Polystyrene Supported Al(OTf)3: a Stable, Efficient, Selective, and Reusable Catalyst for Sulfonylation of Arenes with Sulfonic Acids
Author
Kaveh Parvanak Boroujeni
Keywords
Sulfonylation, Sulfones, Sulfonic acids, Aluminium triflate, Polystyrene
Abstract
Cross-linked polystyrene supported aluminium triflate (Ps-Al(OTf)3) was found to be an efficient and chemoselective heterogeneous Lewis acid catalyst for the direct conversion of arenes to sulfones using sulfonic acids as sulfonylating agents. The solid acid catalyst is stable (as a bench top catalyst) and can be easily recovered and reused without appreciable change in its efficiency.
Page
1887 - 1890
Full Text
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