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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 32, Number 2
BKCSDE 32(2)
February 20, 2011 

 
Title
The Use of Sodium Chlorate/Hydrochloric Acid Mixtures as a Novel and Selective Chlorination Agent
Author
Byung Seok Moon, Han Young Choi, Hun Yeong Koh, Dae Yoon Chi*
Keywords
Sodium chlorate, Chlorination agent, Sodium chlorate/HCl, Chlorination of aromatics, Chlorination of ketones
Abstract
Sodium chlorate/hydrochloric acid mixtures were used to chlorinate activated arenes and the α-position of ketones. This chlorination method was used to produce selectively mono-, di-, and trichlorinated compounds by controlling the molarity of sodium chlorate. This reagent proved to be much more efficient and easier to handle than chlorine gas.
Page
472 - 476
Full Text
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