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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 32, Number 2
BKCSDE 32(2)
February 20, 2011 

 
Title
Simple Synthetic Manipulation Allowing for Morphological Diversity of Porphyrin-Based Microcrystals
Author
Jun Ho Lee, Eui Hyun Ryu, Sungtae Kim, Suk Joong Lee*
Keywords
Amphiphilic, Porphyrin, Building block, Nanocrystalline, CTAB
Abstract
Amphiphilic (porphyrin)Sn(OH)2 molecular building block can directly translate into well-defined solid-state microcrystalline structures. The crystalline diamond plates are obtained from ethanol and crystalline square plates are grown from methanol solution. With a simple synthetic manipulation during the microcrystal growth, the morphologies can be controlled by adopting different molecular packing. Consequently, morphologies of microcrystals have been diversified. Furthermore, the macroscopic crystals were obtained in the presence of cetyltrimethylammonium bromide (CTAB).
Page
609 - 612
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