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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 32, Number 7
BKCSDE 32(7)
July 20, 2011 

Variable Temperature High-Resolution 19F MAS Solid-State NMR Characterization of Fluorocarbon Rubbers
Tae-Joon Park, Sung-Sub Choi, Ji-Sun Kim, Yongae Kim *
Fluorocarbon rubber, 19F NMR, Solid-state NMR
Variable temperature high-resolution 19F magic angle spinning (MAS) solid-state NMR spectroscopy was used to characterize fluorocarbon (FKM) rubbers. The high-resolution spectra of copolymers made from two monomers, vinylidene fluoride and hexafluoropropene, and terpolymers composed of vinylidene fluoride, hexafluoropropene, and tetrafluoroethylene, were obtained using MAS speeds of up to 18 kHz combined with high temperatures of up to 200 °C at a magnetic field strength of 9.4 Tesla. From these high resolution solidstate NMR spectra, we were able to assign the spectral peaks and differentiate the copolymer FKM from the terpolymer FKM. We also determined quantitatively the monomer compositions of each FKM rubber.
2345 - 2350
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