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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 33, Number 4
BKCSDE 33(4)
April 20, 2012 

 
Title
Preparation of Self-Assembled Crystalline Microparticles with Bispyridyl Zn-Porphyrin
Author
Dahee Lee, Suk Joong Lee*
Keywords
Porphyrin, Building block, Pyridine, Crystalline, Morphology
Abstract
Well-defined solid-state microcrystalline structures from bispyridyl Zn-porphyrin have been successfully synthesized. The coordinative interactions between pyridine and Zn are main responsible for this translation of porphyrin molecular building blocks to crystalline microscopic objects. The hexagonal plates are obtained from acetonitrile and rhombus plates are grown from toluene solution. With a simple manipulation during the microcrystal growth, such as growth temperature and time, the morphologies can be controlled by adopting different molecular packing. Consequently, morphologies of microcrystals have been diversified.
Page
1317 - 1320
Full Text
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