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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 33, Number 10
BKCSDE 33(10)
October 20, 2012 

 
Title
Synthesis, Structure and Thermal Properties of Bifurazano[3,4-b:3',4'-f ]furoxano[3'',4''-d]oxacyclohetpatriene (BFFO)
Author
Yanshui Zhou, Kangzhen Xu*, Bozhou Wang*, Hang Zhang, Qianqian Qiu, Fengqi Zhao
Keywords
Bifurazano[3,4-b:3',4'-f ]furoxano[3'',4''-d]oxacyclohetpatriene (BFFO), Furazan, Crystal structure, Thermal properties
Abstract
A novel energetic compound, bifurazano[3,4-b:3',4'-f ]furoxano[3'',4''-d] oxacyclohetpatriene (BFFO), was synthesized through special etherification and its structure was determined by single crystal X-ray diffraction. The crystal of BFFO·H2O is monoclinic, space group P2(1)/c with crystal parameters of a = 9.324(4) Å, b = 9.727(4) Å, c = 10.391(4) Å, β = 106.305(6)°, V = 904.5(6) Å3, Z = 4, μ = 0.17 mm−1, F(000) = 512 and Dc = 1.866 g cm−3. Spectroscopic properties and thermal behaviors of BFFO were studied. BFFO presents good detonation properties.
Page
3317 - 3320
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