Current time in Korea 22:48 Oct 21 (Sat) Year 2017 KCS KCS Publications
KCS Publications
My Journal Log In Register
HOME > Search > Browsing(BKCS) > Archives

Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 33, Number 10
BKCSDE 33(10)
October 20, 2012 

 
Title
Dielectric Study of Allyl Chloride with 2-Pentanone and 2-Hexanone in Microwave Frequency Range
Author
Yuvraj Sudake*, Siddharth Kamble, Aruna Maharolkar, Sunil Patil, Prakash Khirade, Suresh Mehrotra
Keywords
Static dielectric constant, Effective kirkwood correlation factor, Excess static dielectric constant
Abstract
Dielectric measurement on binary mixtures of Allyl chloride (ALC) with 2-Pentanone (2-PE) and 2-Hexanone (2-HE) has been carried out over the entire concentration range using Time Domain Reflectometry (TDR) technique at various temperatures in microwave frequency range of 10 MHz to 10 GHz. The static dielectric constant, excess static dielectric constant ( ), effective Kirkwood correlation factor (geff) of binary mixtures over entire concentration range were determined to study the effect of increasing alkyl group of ketones on hetero molecular interaction. It was found that magnitude of excess static dielectric constant of mixtures increases with increase of alky group of ketones. The study reveals that the dipole moment of Allyl chloride in mixture have antiparallelism tendency where as 2-pentanone and 2-hexanone have parallelism tendency. Excess static dielectric constant is also fitted to Redlich-Kister equation to get information about rates of multimers formation.
Page
3423 - 3426
Full Text
PDF