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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 33, Number 11
BKCSDE 33(11)
November 20, 2012 

 
Title
Pd-Catalyzed Oxidative Arylation of Cinnamylphosphonates: An Efficient Synthesis of (Z)-Alkenylphosphonates
Author
Hyun Seung Lee, Cheol Hee Lim, Hyun Ju Lee, Jae Nyoung Kim*
Keywords
Palladium, Oxidative arylation, Cinnamylphosphonate, Alkenylphosphonates, Morita-Baylis- Hillman adducts
Abstract
Various alkenylphosphonates were prepared via the palladium-catalyzed oxidative arylation of cinnamylphosphonates with arenes. The regioselectivity during the β-H elimination of the corresponding alkylpalladium intermediate was governed most likely by steric factors.
Page
3817 - 3822
Full Text
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