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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 34, Number 1
BKCSDE 34(1)
January 20, 2013 

 
Title
Asymmetric Synthesis of (+)-trans-Aerangis Lactone
Author
Aejin Kim, Satyasheel Sharma, Jong Hwan Kwak, In Su Kim*
Keywords
Aerangis lactone, Asymmetric, Catalytic, Crotylation, Metathesis
Abstract
Asymmetric synthesis of (+)-trans-aerangis lactone was achieved from commercially available 1-hexanol or 1-hexanal in four steps via iridium-catalyzed diastereoselective and enantioselective carbonyl crotylation from the alcohol or aldehyde oxidation level, and ruthenium-catalyzed olefin metathesis.
Page
75 - 78
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