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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 34, Number 2
BKCSDE 34(2)
February 20, 2013 

Synthesis of N-Azaaryl Anilines: An Efficient Protocol via Smiles Rearrangement
Shuai Xia, Li-Ying Wang, Heng-Zhi Sun, Huan Yue, Xiu-Hua Wang, Jia-Lian Tan, Yin Wang, Di Hou, Xiao-Yan He, Ki-Cheol Mun, B. Prem Kumar, Hua Zuo*, Dong-Soo Shin*
Smiles rearrangement, N-Azaaryl anilines, Amine, Phenol, Synthesis
An efficient process for the synthesis of N-azaaryl anilines via Smiles rearrangement as a tool. A variety of Nazaaryl anilines were generated by the reaction of substituted phenols, substituted anilines, aminopyridines and chloroacetyl chloride or pyridols, under base condition in good to excellent yields.
394 - 398
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