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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 35, Number 2
BKCSDE 35(2)
February 20, 2014 

 
Title
Fluoroethylene Carbonate Addition Effect on Electrochemical Properties of Mixed Carbonate-based Organic Electrolyte Solution for a Capacitor
Author
Mingyeong Kim, Ick-Jun Kim, Sunhye Yang, Seok Kim*
Keywords
Fluoroethylene carbonate, Organic electrolytes, Electrochemical property, Cyclic voltammetry, Capacitance
Abstract
In this paper, organic solvent electrolytes were prepared by a mixture of propylene carbonate (PC), dimethyl carbonate (DMC), tetraethylammonium tetrafluoroborate (TEABF4) as a salt, and by containing a different content of fluoroethylene carbonate (FEC) as an additive agent. The aim of this paper is to evaluate the ionic properties of propylene carbonate (PC)/dimethyl carbonate (DMC) mixtures as solvents for a capacitor application, in view of improving the electrochemical performances. The bulk resistance and interfacial resistance of the mixture electrolytes were investigated using an AC impedance method. The morphology of carbon-based electrodes which were contained in different electrolytes was analyzed by scanning electron microscopy (SEM) method. From the experimental results, by increasing the FEC content, capacitance of electrodes was increased, and the interfacial resistance was decreased. In particular, by a content of 2 vol % FEC in 0.2 M TEABF4 PC/DMC solvent, the electrolyte showed the superior capacitance. However, when FEC content exceeds 2 vol %, the capacitance was decreased and the interfacial resistance was increased.
Page
466 - 470
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