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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 35, Number 5
BKCSDE 35(5)
May 20, 2014 

 
Title
Development of Palladium, Gold and Gold-Palladium Containing Metal-Carbon Nanoreactors: Hydrogen Adsorption
Author
Vishal J. Mayani, Suranjana V. Mayani, Sang Wook Kim*
Keywords
Carbon cage, Hydrogen adsorption, Metal carbon nanoreactors, Metal-doped
Abstract
Metal-carbon nanoreactors (MCNRs) were prepared from a pristine carbon cage (CC) using a simple and efficient template method with nano silica ball (NSB), pyrolysis fuel oil (PFO) and transition metals, such as palladium and gold. Metal nanoparticles were embedded in approximately 25 and 170 nm sized, highly ordered carbon cages. The newly developed Pd, Au and Au–Pd doped carbon nanoreactors were characterized by microanalysis, N2 adsorption–desorption isotherm, powder X-ray diffraction (XRD), thermo-gravimetric analysis (TGA), scanning electron microscopy coupled with energy dispersive spectroscopy (SEM-EDS), transmission electron microscopy and inductively coupled plasma (ICP) analysis. The ordered MCNRs have exhibited dynamic hydrogen adsorption capability compared to the carbon cage.
Page
1312 - 1316
Full Text
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