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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 35, Number 7
BKCSDE 35(7)
July 20, 2014 

 
Title
Synthesis of Novel Chiral Diamino Alcohols and Their Application in Copper-Catalyzed Asymmetric Allylic Oxidation of Cycloolefins
Author
Laleh Faraji, Saadi Samadi, Khosrow Jadidi*, Behrouz Notash
Keywords
Chiral diamino alcohols, Chiral hydroxyldiamides, Asymmetric allylic oxidation, Small chiral libraries, Chiral pool amino acids
Abstract
The small library of new enantiomerically pure (S,S)-diamino alcohols 1 and their hydroxyldiamide precursors 2 were conveniently synthesized on a gram scale from inexpensive and commercially chiral pool amino acids. The catalytic and induced asymmetric effects of the chiral ligands 1 in the asymmetric allylic oxidation of cycloolefins were investigated.
Page
1989 - 1995
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