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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 35, Number 9
BKCSDE 35(9)
September 20, 2014 

Cyanide- and Phenoxo-Bridged Heterobimetallic Fe(III)-Mn(III) Coordination Polymer: Synthesis, Crystal Structures and Magnetic Properties
Daopeng Zhang*, Lingqian Kong, Yueyun Li, Ping Wang, Xia Chen
Cyanide-bridged, Heterometallic, Crystal structure, Magnetic property
Two two-dimensional cyanide- and phenoxo-bridged heterometallic M(II)-Mn(III) (M = Ni, Pd) coordination polymers {[Mn(saltmen)]4[Ni(CN)4]}(ClO4)2·CH3OH·H2O (1) and {[Mn(saltmen)]4[Pd(CN)4]}(ClO4)2· CH3CN·H2O (2) (saltmen2– = N,N'-(1,1,2,2-tetramethylethylene)bis(salicylideneaminato)dianion) have been obtained by using K2[M(CN)4] as building blocks and a salen-tpye Schiff-base manganese(III) compound as assembling segment. Single X-ray analysis reveals their isostrutural cyanide-bridged MMn4 pentanuclear cationic structure. The four Schiff base manganese units of the pentanuclear entity are self-complementary through the phenoxo oxygen atoms from the neighboring complex, therefore forming cyanide- and phenoxobridged 2D sheet-like structure. Investigation over magnetic susceptibilities reveals the overall ferromagnetic coupling between the adjacent Mn(III) ions bridged by the phenoxo oxygen atoms with J = 2.13 and 2.21 cm−1 for complexes 1 and 2, respectively.
2684 - 2688
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