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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 17, Number 3
BKCSDE 17(3)
March 20, 1996 

 
Title
Solvolysis of 1-(4-methoxyphenyl)-1-aryl-2,2,2-trifluoroethyl chlorides
Author
Soo-Dong Yoh, Jeong Min Kweon, Sung Il Byeon, Mizue Fujio, Masaaki Mishima, Yuho Tsuno
Keywords
Abstract
The rates of solvolysis of 1-(4-methoxyphenyl)-1-aryl-2,2,2-trifluoroethyl chlorides[I] in a variety of solvents were measured by an electroconductometric method. LArSR relationships (Yukawa-Tsuno eq.)were found to give a linear plot, log(k/ko)=-1.84[σ o+0.918(σ+-σo)], in 80% aqueous ethanol. Small
Page
228 - 234
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