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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 18, Number 10
BKCSDE 18(10)
October 20, 1997 

 
Title
Synthesis and Mesomorphic Properties of Palladium(Ⅱ) Complexes Based on 3,4,5-Trialkoxy Benzonitrile Ligands
Author
Myongsoo Lee*, Yong-Sik Yoo, Moon-Gun Choi
Keywords
Abstract
The synthesis and characterization of the nitrile ligands 3,4,5-tridodecyloxy benzonitrile (7) and 3,4,5-trioctadecyloxy benzonitrile (8), and their corresponding palladium(Ⅱ) complexes are described. The nitrile ligands display only a crystalline phase and do not show liquid crystalline behavior, while their corresponding palladium(Ⅱ) complexes dispaly an enantiotropic columnar mesophase. The induction of the columnar mesophase is mainly due to dimerization through the palladium complexation of the half disk-like nitrile ligands giving rise to a trans square planar geometry.
Page
1067 - 1070
Full Text
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