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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 19, Number 9
BKCSDE 19(9)
September 20, 1998 

 
Title
Reconstruction of Pd Particles supported on Silica in the Presence of CO as Studied by Carbon-13 NMR
Author
Oc Hee Han, Gary L. Haller, Kurt W. Zilm
Keywords
Abstract
The 13C NMR spectrum of 13CO adsorbed on Pd particles varies dramatically depending on dispersion. The spectrum of highly dispersed Pd particles supported on silica is a powder pattern ∼800 ppm wide with a first moment of 410 ppm. A low dispersion sample has a motionally narrowed line centered at 750±30 ppm and only ∼85 ppm full width at half height (FWHH). Over several years, high dispersion samples show an increase in the intensity near 750 ppm. These observations are interpreted as an increase of mobile bridging CO on high dispersion Pd surfaces of particles which resulted from smoothing of the metal particle surfaces in the presence of CO.
Page
942 - 947
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