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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 19, Number 12
BKCSDE 19(12)
December 20, 1998 

 
Title
Characteristics of the Low Frequency Sequence Bands Observed in the Vibronic Emission Spectra of the Jet Cooled p-Fluorobenzyl Radical in the D1→D0 Transition
Author
Dae Youl Baek, Sang Kuk Lee
Keywords
Abstract
The p-fluorobenzyl radical was generated from the p-fluorotoluene and vibronically excited in a corona excited supersonic expansion with inert buffer gases. The vibronic emission spectra of the jet cooled p-fluorobenzyl radical in the D1 → D0 transition have been observed in the visible region. The spectra exhibit several low frequency sequence bands in the vicinity of the every strong vibronic band. The characteristics of the sequence bands have been examined by varying the experimental conditions such as carrier gas and nozzle size to identify the origin of the transition in the spectra.
Page
1359 - 1363
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