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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 27, Number 5
BKCSDE 27(5)
May 20, 2006 

 

613  

Chemical Modification of Nucleic Acids toward Functional Nucleic Acid Systems
Natarajan Venkatesan, Young Jun Seo, Eun Kyoung Bang, Sun Min Park, Yoon Suk Lee, Byeang Hyean Kim*
Keywords: Nucleoside, Nucleotide, Oligonucleotide, Nucleic acid
DOI: https://doi.org/10.5012/bkcs.2006.27.5.613

Abstract | Full Text: PDF


631  

Hydroarylation for the Facile Synthesis of 2-Substituted Tetrahydroquinoline: A Concise Synthesis of (+)-(S)-Angustureine
Jae-Sang Ryu
Keywords: Hydroarylation, Tetrahydroquinoline, (+)-(S)-Angustureine
DOI: https://doi.org/10.5012/bkcs.2006.27.5.631

Abstract | Full Text: PDF


633  

Practical Synthesis of Au Nanowires via a Simple Photochemical Route
Yeong-Joon Kim, Jae Hee Song*
Keywords: Au, Nanowires, Photochemistry
DOI: https://doi.org/10.5012/bkcs.2006.27.5.633

Abstract | Supporting Information | Full Text: PDF


635  

New Rhenium Octahedral Cluster Sulfido-cyanide Chain Polymer: The Synthesis and Crystal Structure of Cs4[{Re6S8}(CN)4S2/2]
N. G. Naumov*, S.-J. Kim*, A. V. Virovets, Y. V. Mironov, V. E. Fedorov
Keywords: Rhenium, Cluster, Cyanide, Polymer, Crystal structure
DOI: https://doi.org/10.5012/bkcs.2006.27.5.635

Abstract | Full Text: PDF


637  

Enantioseparation by Sonochromatography
Jae Jeong Ryoo*, Young-Ae Song, Young Han Jeong, Myung Ho Hyun, Jung Hag Park, Wonjae Lee
Keywords: Chiral separation, Ultrasonic dependence, Various temperature, Sonochromatography
DOI: https://doi.org/10.5012/bkcs.2006.27.5.637

Abstract | Full Text: PDF


642  

Substrate Construes the Copper and Nickel Ions Impacts on the Mushroom Tyrosinase Activities
N. Gheibi, A. A. Saboury*, K. Haghbeen
Keywords: Mushroom tyrosinase, Monophenols, Diphenols, Nickel, Copper
DOI: https://doi.org/10.5012/bkcs.2006.27.5.642

Abstract | Full Text: PDF


649  

Analytical Head-space Supercritical Fluid Extraction Methodology for the Determination of Organochlorine Compounds in Aqueous Matrix
Keon Sang Ryoo*, Seong-Oon Ko, Yong Pyo Hong, Jong-Ha Choi, Yonggyun Kim, Won Kyoung Lee
Keywords: Head-space SFE methodology, Organochlorine compounds, Conventional method, Static and dynamic mode
DOI: https://doi.org/10.5012/bkcs.2006.27.5.649

Abstract | Full Text: PDF


657  

Efficient Target Site Selection for an RNA-cleaving DNAzyme through Combinatorial Library Screening
Ki-Sun Kim, Woo-Hyung Choi, Soo-Jeong Gong, Sangtaek Oh, Jae Hyun Kim, Dong-Eun Kim*
Keywords: Antisense oligonucleotide, 10-23 DNAzyme, DNAzyme library, Gene inactivation, RNA cleavage
DOI: https://doi.org/10.5012/bkcs.2006.27.5.657

Abstract | Full Text: PDF


663  

Carnosine and Related Compounds Protect against the Hydrogen Peroxide-Mediated Cytochrome c Modification
Jung Hoon Kang
Keywords: Cytochrome c, Oligomerization, Free radical scavenger, Carnosine
DOI: https://doi.org/10.5012/bkcs.2006.27.5.663

Abstract | Full Text: PDF


667  

Selective Reduction of Carbonyl Compounds with B-Acetoxy- and B-Trifluoroacetoxydiisopinocampheylboranes
Jin Soon Cha*, Ho Tae Nam, Seung Jin Park, Sang Yong Kwon, Oh Oun Kwon
Keywords: Selective reduction, B-Acetoxydiisopinocampheylborane, B-Trifluoroacetoxydiisopinocampheylborane, MPV type reduction, Carbonyl compounds
DOI: https://doi.org/10.5012/bkcs.2006.27.5.667

Abstract | Full Text: PDF


672  

Immobilization of Horseradish Peroxidase to Electrochemically Deposited Gold-Nanoparticles on Glassy Carbon Electrode for Determination of H2O2
Hyunwoo Ryoo, Yousung Kim, Junghyun Lee, Woonsup Shin, Noseung Myung, Hun-Gi Hong*
Keywords: Gold-nanoparticles, Glassy carbon electrode, Horseradish peroxidase, Hydrogen peroxide
DOI: https://doi.org/10.5012/bkcs.2006.27.5.672

Abstract | Full Text: PDF


679  

Synthesis and Crystal Structure of Lead Iodide in the Sodalite Cavities of Zeolite A (LTA)
Seok Han Kim, Woo Taik Lim*, Ghyung Hwa Kim, Heung Soo Lee, Nam Ho Heo*
Keywords: Zeolite A, Lead iodide, Single-crystal X-ray diffraction, Crystal structure
DOI: https://doi.org/10.5012/bkcs.2006.27.5.679

Abstract | Supporting Information | Full Text: PDF


687  

Syntheses and Characterization of Cr(III)-Hydrogensalicylato and -Hydroxonitrophenolato Tetraaza Macrocyclic Complexes
Jong Chul Byun*, Chang Hoon Yoon, Dae Hun Mun, Ki Ju Kim, Yu Chul Park
Keywords: Macrocyclic Cr(III) complex, Crystal structure, Salicylate, Nitrophenolate
DOI: https://doi.org/10.5012/bkcs.2006.27.5.687

Abstract | Full Text: PDF


694  

Speciation of Cr(III)/Cr(VI) in Tannery Waste Waters by Using Ion-Exchange Resins
S. Kartal*, S. Tokallog˘ l u , B. Ozkan
Keywords: Speciation, Cr(III)/(VI), Tannery waste water, Ion-exchange resin
DOI: https://doi.org/10.5012/bkcs.2006.27.5.694

Abstract | Full Text: PDF


699  

Selection and Analysis of Genomic Sequence-Derived RNA Motifs Binding to C5 Protein
Kwang-sun Kim, Hyejin Ryoo, June Hyung Lee, Meehyun Kim, Taeyeon Kim, Yool Kim, Kook Han, Seol-Hoon Lee, Younghoon Lee*
Keywords: C5 protein, Genomic SELEX, Aptamer, RNA-protein interaction, M1 RNA
DOI: https://doi.org/10.5012/bkcs.2006.27.5.699

Abstract | Full Text: PDF


705  

Synthesis and Antibacterial Activity of 1β-Methyl-2-[5-(1,2-disubstituted ethyl)-pyrrolidin-3-ylthio]carbapenem Derivatives. Part III
Jung-Hyuck Cho, Soo-Hyun Ahn, Heechol Jeon, So Young Kim, Chang-Hyun Oh*
Keywords: 1β-Methylcarbapenem, Antibacterial activity, Substituent effect
DOI: https://doi.org/10.5012/bkcs.2006.27.5.705

Abstract | Full Text: PDF


713  

Macrocyclic Isomers with S2O-Donor Set as Silver(I) Ionophores
Sung Bae Park, Il Yoon, Joobeom Seo, Hyun Jee Kim, Jae Sang Kim, Shim Sung Lee*
Keywords: Isomeric S2O macrocycles, Solvent extraction, Ag(I)-ISE, NMR, Sandwich-type silver(I) complex
DOI: https://doi.org/10.5012/bkcs.2006.27.5.713

Abstract | Full Text: PDF


718  

Characterization of Heterogeneous Interaction Behaviour in Ternary Mixtures by Dielectric Analysis: The H-Bonded Binary Polar Mixture in Non-Polar Solvent
R. J. Sengwa*, Madhvi, Sonu Sankhla, Shobha Sharma
Keywords: Heterogeneous interaction, Dielectric constant, Kirkwood correlation factor, Excess dielectric parameters
DOI: https://doi.org/10.5012/bkcs.2006.27.5.718

Abstract | Full Text: PDF


725  

The Use of Phenanthraquinone Monophenyl Thiosemicarbazone for Preconcentration, Ion Flotation and Spectrometric Determination of Zinc(II) in Human Biofluids and Pharmaceutical Samples
Magda Ali Akl
Keywords: Ion flotation, Preconcentration, Zn(II), Biofluids, Drugs
DOI: https://doi.org/10.5012/bkcs.2006.27.5.725

Abstract | Full Text: PDF


733  

Kinetic and Mechanism of the Addition of Benzylamines to α-Phenyl-β-thiophenylacrylonitriles in Acetonitrile
Jaeyoung Hwang, Kiyull Yang, In Sun Koo*, Dae Dong Sung, Ikchoon Lee
Keywords: Nucleophilic addition reaction, Cross-interaction constant, Kinetic isotope effects, Four-center cyclic transition state
DOI: https://doi.org/10.5012/bkcs.2006.27.5.733

Abstract | Full Text: PDF


739  

Synthesis and Anion Recognition of Cholic Acid-based Tripodal Receptor: A Chloride Selective Anion Receptor
Ki Soo Kim, Nam Ju Cho, Hong-Seok Kim*
Keywords: Cholic acid, Urea, Hydrogen bonds, Anion recognition, Chloride ion
DOI: https://doi.org/10.5012/bkcs.2006.27.5.739

Abstract | Full Text: PDF


744  

Carboxylation of Styrene Oxide Catalyzed by Quaternary Onium Salts under Solvent-free Conditions
Jae-Jin Shim, Duck Kim, Choon Sup Ra*
Keywords: Carbon dioxide, Styrene oxide, Atom economy, Solvent-free condition, Quaternary onium salt
DOI: https://doi.org/10.5012/bkcs.2006.27.5.744

Abstract | Full Text: PDF


747  

d10 Metal Complexes of a Tripodal Amine Ligand
Kyu Seong Choi, Donghyun Kang, Ji-Eun Lee, Joobeom Seo, Shim Sung Lee*
Keywords: Tripodal amine ligand, d10 Metal ions, Complex, Crystal structure, NMR
DOI: https://doi.org/10.5012/bkcs.2006.27.5.747

Abstract | Full Text: PDF


751  

Intramolecular Energy Transfer in a Bichromophoric System, Zinc meso-Tetratolylporphyrin Covalently Linked to Anthracene through Ethylene Linkage
Eun Ju Shin
Keywords: Porphyrin, Anthracene, Fluorescence, Intramolecular energy transfer
DOI: https://doi.org/10.5012/bkcs.2006.27.5.751

Abstract | Full Text: PDF


755  

A Facile Synthesis of Optically Active Four Stereoisomers of 1-Aminobenz[f]indan-2-ol
Ying Xue Jin, Guanghui Tan, Hee Jung Choi, Myung Ho Hyun*
Keywords: 1-Aminobenz[f]indan-2-ol, Kinetic resolution, Kinetic transesterification, Lipase PS
DOI: https://doi.org/10.5012/bkcs.2006.27.5.755

Abstract | Full Text: PDF


759  

Synthesis and Structural Characterization of Novel Organohydroborate Hafnocene Complex (η5-C5H5)2Hf{(μ-H)2BC8H14)}Cl
Jang-Hoon Chung*, Sang Mock Lee
Keywords: Organohydroborate, Hafnocene, Metallocene
DOI: https://doi.org/10.5012/bkcs.2006.27.5.759

Abstract | Full Text: PDF


762  

CdSe Thin Films Grown by MOCVD Method Using New Single-source Precursors
Dong Yock Chae, Kook Won Seo, Seung Soo Lee, Seok Hwan Yoon, Il-Wun Shim*
Keywords: Cadmium selenide, CdSe, Diselenocarbamate, MOCVD, Single-source precursor
DOI: https://doi.org/10.5012/bkcs.2006.27.5.762

Abstract | Full Text: PDF


765  

Mechanistic Studies on the O2-mediated Oxidation of Olefins in the Presence of (Schiff-base)Mn(III) Catalyst and NaBH4
Jong Seok Baik, Nam Ho Lee*
Keywords: Mechanism, Molecular oxygen, Oxygenation, (Schiff-base)Mn(III) complex, Sodium borohydride
DOI: https://doi.org/10.5012/bkcs.2006.27.5.765

Abstract | Full Text: PDF


769  

α-Vinylation of Haloquinones with Methyl Acrylate and MVK under Baylis-Hillman Reaction Conditions
Seung Won Lee, Chang Hoon Lee, Kee-Jung Lee*
Keywords: Vinylation, Haloquinones, Baylis-Hillman Reaction, Anthraquinone
DOI: https://doi.org/10.5012/bkcs.2006.27.5.769

Abstract | Full Text: PDF


773  

Palladium-Catalyzed Asymmetric Allylic Alkylation Using Ephedrine-derived Phosphinooxazolidines
Myung-Jong Jin*, M. S. Sarkar, Ji-Young Jung, Dong-Hwan Lee, Ik-Mo Lee
Keywords: Asymmetric catalysis, Allylic substitution, Ephedrine, Phosphinooxazolidine
DOI: https://doi.org/10.5012/bkcs.2006.27.5.773

Abstract | Full Text: PDF


776  

Potassium Hydroxide-Mediated Cascade Isomerization and Oxy-Michael Addition of 3-(2-Hydroxymethylphenyl)-1-arylprop-2-yn-1-ols Leading to Isobenzofurans
Chan Sik Cho*, Sang Chul Shim*
Keywords: 2-Alkynylbenzyl alcohols, Cycloisomerization, Isobenzofurans, Isomerization, Potassium hydroxide
DOI: https://doi.org/10.5012/bkcs.2006.27.5.776

Abstract | Full Text: PDF


779  

Two New Fungal Metabolites from an Epiphytic Fungus Paraphaeosphaeria Species
Hyang Burm Lee, Hyuncheol Oh*
Keywords: Epiphytic fungi, Fungal metabolites, Structure determination, NMR
DOI: https://doi.org/10.5012/bkcs.2006.27.5.779

Abstract | Full Text: PDF


783  

The Effect of β -Cyclodextrine on the Diastereoselective NaBH4 Reduction of Cyclohexanone Derivatives
Myung Soo Seo, Sang Hee Lee*
Keywords: Reduction, β-Cyclodextrine, Sodium borohydride, Diastereoselectivity, Cyclohexanone
DOI: https://doi.org/10.5012/bkcs.2006.27.5.783

Abstract | Full Text: PDF


786  

Structure Analysis of Self-Kinasing Ribozyme
Bongrae Cho
Keywords: RNase T1, RNase V1, Kethoxal, Fe(II)-EDTA
DOI: https://doi.org/10.5012/bkcs.2006.27.5.786

Abstract | Full Text: PDF


789  

Dehydrogenation of Ethylbenzene with Carbon Dioxide over Supported Vanadium- Antimony Oxide Catalysts: Effect of Zirconia Modification in Alumina Support
Do-Young Hong, Vladislav P. Vislovskiy, Yeung-Ho Park, Jong-San Chang*
Keywords: Ethylbenzene, Dehydrogenation, Carbon dioxide, V-Sb oxide catalysts, ZrO2-modified alumina support
DOI: https://doi.org/10.5012/bkcs.2006.27.5.789

Abstract | Full Text: PDF


793  

Identification of Phospholipid Molecular Species in Porcine Brain Extracts Using High Mass Accuracy of 4.7 Tesla Fourier Transform Ion Cyclotron Resonance Mass Spectrometry
Seonghyun Yu, Kun Cho, Young Hwan Kim, Soojin Park, Jaedong Kim, Han Bin Oh*
Keywords: Fourier-transform ion cyclotron resonance mass spectrometer (FTICR-MS), Phospholipid (PL), Lipid, Lipidomics, High mass accuracy
DOI: https://doi.org/10.5012/bkcs.2006.27.5.793

Abstract | Supporting Information | Full Text: PDF