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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 28, Number 11
BKCSDE 28(11)
November 20, 2007 

 

1902  

New Design in Homogeneous Palladium Catalysis: Study of Transformation of Group 14 Element Compounds and Development of Nanosize Palladium Catalysts
Yasushi Tsuji, Tetsuaki Fujihara
Keywords: Palladium, Homogeneous catalysis, Group 14 element compounds, Nanosize
DOI: https://doi.org/10.5012/bkcs.2007.28.11.1902

Abstract | Full Text: PDF


1910  

Boronated Porphyrins and Chlorins as Potential Anticancer Drugs
Valentina A. Ol'shevskaya, Andrey V. Zaytsev, Arina N. Savchenko, Alexander A. Shtil, Chan Seong Cheong, Valery N. Kalinin*
Keywords: Carboranes, Porphyrins, Drug resistance, Photodynamic therapy, Boron neutron capture therapy
DOI: https://doi.org/10.5012/bkcs.2007.28.11.1910

Abstract | Full Text: PDF


1917  

Thiobarbituric Acid Derivatives for Anti-HCV Agents Targeting NS5B RNA Polymerase
Hyun-Joon Ha*, Sang-Mi Han, Seung Whan Ko, Kyung Eun Cha, Jong-Ho Lee, Heejoon Myung
Keywords: Thiobarbituric acid, HCV, NS5B RNA polymerase, Inhibition
DOI: https://doi.org/10.5012/bkcs.2007.28.11.1917

Abstract | Full Text: PDF


1919  

Intramolecular [4+2] Cycloaddition Reactions Catalyzed by Rhodium Catalysts Derived from a Rhodium Anion Precursor
Sang Ick Lee, Se Yeon Park, Ji Hoon Park, Young Keun Chung*, Jin Wook Han*
Keywords: Rhodium-catalyst, Cycloaddition, Rhodium anion precursor, Dienyne
DOI: https://doi.org/10.5012/bkcs.2007.28.11.1919

Abstract | Full Text: PDF


1921  

A Highly Diastereoselective Cyclocarbonylation of Allene-Aldehyde
Mediated by Mo(CO)6: Synthesis of Bicyclic Lactones
Kyoung-Jun Ko, Sang-Hoon Kim, Yurim Kim, Dongwon Min, Chan-Mo Yu*
Keywords: Allene, Cyclocarbonylation, Diastereoselectivity, Lactone, Molybdenum
DOI: https://doi.org/10.5012/bkcs.2007.28.11.1921

Abstract | Full Text: PDF


1923  

Expanded Fluorescent Nucleoside Analog as Hybridization Probe
Young Jun Seo, Sankarprasad Bhuniya, Subhasish Tapadar, Jeong Wu Yi, Byeang Hyean Kim*
Keywords: Fluorescence, Nucleoside, Oligonucleotide, Hybridization probe
DOI: https://doi.org/10.5012/bkcs.2007.28.11.1923

Abstract | Full Text: PDF


1925  

Palladium Catalysts Supported onto the Ionic Liquid-Functionalized Carbon Nanotubes for Carbon-Carbon Coupling
Min Jung Park, Sang-gi Lee*
Keywords: Palladium catalyst, Ionic liquid, CNT, Immobilization, Carbon-carbon coupling
DOI: https://doi.org/10.5012/bkcs.2007.28.11.1925

Abstract | Full Text: PDF


1927  

Novel Syntheses of [6,7,n]-Benzazepinone and [6,6,n]-Benzophenanthridinone
Derivatives by Rhodium-catalyzed Cyclization of o-(n-Cyanoalkynyl)benzaldehydes
Chang Ho Oh*, Katta Venugopal Reddy
Keywords: Benzazepinone, Phenanthridinone, Rhodium, Cyclization
DOI: https://doi.org/10.5012/bkcs.2007.28.11.1927

Abstract | Full Text: PDF


1929  

Cooperative Catalysis by Indium and Palladium for the Allyl Cross-Coupling Reactions
Jae-Young Lee, Phil Ho Lee*
Keywords: Catalysis, Cross-coupling, Indium, Palladium, Manganese
DOI: https://doi.org/10.5012/bkcs.2007.28.11.1929

Abstract | Full Text: PDF


1931  

Synthesis and Properties of Soluble and Stable Silyl End-capped Bis-thienylanthracene Oligomers
Jung Hei Choi, Dae Won Cho, Nam Kyoung Sung, Sung-Ho Jin, Ung Chan Yoon*
Keywords: Thiophene oligomer, Bis-oligothienylanthracene, Silyl end-capping group, Stille reaction
DOI: https://doi.org/10.5012/bkcs.2007.28.11.1931

Abstract | Full Text: PDF


1939  

Synthesis and Mesomorphic Properties of New Achiral Liquid Crystals with 3-Alkoxy-2-(alkoxymethyl)-1-propoxy Swallow-Tails
Kyung-Tae Kang*, Jeong Tak Kim, Ryeo Yun Hwang, Song Ju Park, Seng Kue Lee, Jong Gun Lee, Yong Bae Kim
Keywords: Liquid crystal, Swallow-tailed liquid crystal, Antiferroelectric-like phase, 3-Alkoxy-2-(alkoxymethyl)-1-propanol
DOI: https://doi.org/10.5012/bkcs.2007.28.11.1939

Abstract | Full Text: PDF


1945  

Fluorene-Based Conjugated Copolymers Containing Hexyl-Thiophene Derivatives for Organic Thin Film Transistors
Hoyoul Kong, Dae Sung Chung, In-Nam Kang, Eunhee Lim, Young Kwan Jung, Jong-Hwa Park, Chan Eon Park*, Hong-Ku Shim*
Keywords: Fluorene, Thiophene, Organic thin-film transistor (OTFT)
DOI: https://doi.org/10.5012/bkcs.2007.28.11.1945

Abstract | Full Text: PDF


1951  

A Novel Acid-Base Catalyzed Sol-Gel Synthesis of
Highly Active Mesoporous TiO2 Photocatalysts
Romana Khan, Sun Woo Kim, Tae-Jeong Kim*, Hyosun Lee
Keywords: Photocatalyst, TiO2, Sol-gel, Mesoporous, Toluene degradation
DOI: https://doi.org/10.5012/bkcs.2007.28.11.1951

Abstract | Full Text: PDF


1958  

Synthesis and Characterization of Ir(H)(CO)(PEt3)2(η2-C60)
Chang Yeon Lee, Gaehang Lee, Hongkyu Kang, Bo Keun Park, Joon T. Park*
Keywords: Metallofullerene, Iridium, Crystal structure, Cyclic voltammetry
DOI: https://doi.org/10.5012/bkcs.2007.28.11.1958

Abstract | Full Text: PDF


1963  

Synthesis of Silafluorene on Dendritic Periphery
Chungkyun Kim*, Wonju Seo, Myeong-Jin Oh
Keywords: Dendrimer, Silane, Silafluorene, Hydrosilation, Luminescence
DOI: https://doi.org/10.5012/bkcs.2007.28.11.1963

Abstract | Full Text: PDF


1967  

Ultrafast Time-Resolved Laser Spectroscopic Studies of trans-Bis(ferrocene-carboxylato)(tetraphenyl-porphyrinato)tin(IV): Intramolecular Electron-Transfer Dynamics
Joon Hee Jang, Hee Jung Kim, Hee-Joon Kim, Chul Hoon Kim, Taiha Joo, Dae Won Cho, Minjoong Yoon*
Keywords: Ferrocene-Sn-porphyrin, Photoinduced electron transfer, Ultrafast laser spectroscopy
DOI: https://doi.org/10.5012/bkcs.2007.28.11.1967

Abstract | Full Text: PDF


1973  

Synthesis of Novel Organic Dyes Containing Coumarin Moiety for Solar Cell
Hyunbong Choi, Chul Baik, Hyun Jun Kim, Jeum-Jong Kim, Kihyung Song, Sang Ook Kang*, Jaejung Ko*
Keywords: Fluorenyl, Coumarin, Organic dyes, Solar cell
DOI: https://doi.org/10.5012/bkcs.2007.28.11.1973

Abstract | Full Text: PDF


1980  

Liquid Chromatographic Resolution of N-(3,5-Dinitrobenzoyl)-α-amino Acids
on a New Chiral Stationary Phase: the First Liquid Chromatographic Utilization of
a Double-Ureide Pocket for the Recognition of Chiral Carboxylate Anions
Myung Ho Hyun*, Seung Nam Kim, Hee Jung Choi, Pachgounder Sakthivel
Keywords: Chiral stationary phase, Chiral carboxylate anion, Liquid chromatography, N-(3,5-Dinitrobenzoyl)-
α-amino acids

DOI: https://doi.org/10.5012/bkcs.2007.28.11.1980

Abstract | Full Text: PDF


1985  

Analysis of Heavy Metal Toxic Ions by Adsorption onto Amino-functionalized Ordered Mesoporous Silica
Ali Md Showkat, Yu-Ping Zhang, Min Seok Kim, Anantha Iyengar Gopalan, Kakarla Raghava Reddy, Kwang-Pill Lee*
Keywords: Mesoporous, Textural parameters, Adsorbent, Heavy metal ions, MCM-41
DOI: https://doi.org/10.5012/bkcs.2007.28.11.1985

Abstract | Full Text: PDF


1993  

Substitution Effect on Electronic Transition of Bi-substituted Benzyl-type Radicals: Symmetric Substitution
Hyeon Geun Ahn, Gi Woo Lee, Tae Kyu Kim, Sang Kuk Lee*
Keywords: Spectroscopy, Benzyl-type radical, Substitution effect
DOI: https://doi.org/10.5012/bkcs.2007.28.11.1993

Abstract | Full Text: PDF


1996  

Electrochemical Study of [Ni6(μ3-Se)2(μ4-Se)3(dppf)3] Cluster and Its Catalytic Activity towards the Electrochemical Reduction of Carbon Dioxide
Deog-Su Park, Md. Abdul Jabbar, Hyun Park, Hak Myoung Lee, Sung-Chul Shin, Yoon-Bo Shim*
Keywords: Redox behavior of metal cluster, Surface modification, Electrocatalysis, Electrochemical reduction of CO2
DOI: https://doi.org/10.5012/bkcs.2007.28.11.1996

Abstract | Full Text: PDF


2003  

Anilinolysis of Diphenyl Thiophosphinic Chloride and Theoretical Studies
on Various R1R2P(O or S)Cl†
Nilay Kumar Dey, In-Suk Han, Hai Whang Lee*
Keywords: Anilinolysis of diphenyl thiophosphinic chloride, Frontside nucleophilic attack, Deuterium kinetic isotope effect, NBO charge, Degree of distortion
DOI: https://doi.org/10.5012/bkcs.2007.28.11.2003

Abstract | Full Text: PDF


2009  

Solvent Effect on the Nature of the Metallamacrocycles Formed: Formation of Octanuclear and Dodecanuclear Manganese Metalladiazamacrocycles
Rohith P. John, Kyungjin Lee, Kyungjae Lee, Mira Park, Myoung Soo Lah*
Keywords: Self-assembly, Molecular polygon, Octanuclear metallamacrocycle, Dodecanuclear metallamacrocycle, Solvent effect
DOI: https://doi.org/10.5012/bkcs.2007.28.11.2009

Abstract | Full Text: PDF


2015  

Synthesis of Ferrocenyl and Diphenyl Substituted Bispyridino-18-Crown-6 Ether for Chiral Recognition
Sunjin Jo, Youngeup Jin, Jaehong Kim, Hongsuk Suh*
Keywords: Chiral crown ether, Bispyridine-18-crown-6, Chiral recognition, Ferrocenyl group, Chemical sensor
DOI: https://doi.org/10.5012/bkcs.2007.28.11.2015

Abstract | Full Text: PDF


2020  

Solvent-free Microwave-Assisted Ortho-Alkylation of Aromatic Ketimine with Acrylic Acid Derivatives by Rh(I) Catalyst
Eun-Ae Jo, Jeong-Ae Ahn, Chul-Ho Jun*
Keywords: ortho-alkylation, Microwave, Rhodium, Homogeneous catalyst, Ketimine
DOI: https://doi.org/10.5012/bkcs.2007.28.11.2020

Abstract | Full Text: PDF


2025  

Polymer-supported Zinc Tetrahalide Catalysts for the Coupling Reactions
of CO2 and Epoxides
Bora Lee, Nan Hee Ko, Byoung Sung Ahn, Minserk Cheong, Hoon Sik Kim*, Je Seung Lee*
Keywords: Ionic liquids, Zinc tetrahalide, Ethylene carbonate, Propylene carbonate, Polymer-supported
DOI: https://doi.org/10.5012/bkcs.2007.28.11.2025

Abstract | Full Text: PDF


2029  

Microwave Synthesis of Hydrotalcite by Urea Hydrolysis
Zhiqiang Yang, Kwang-Min Choi, Nanzhe Jiang, Sang-Eon Park*
Keywords: Hydrotalcite, Urea hydrolysis, Microwave
DOI: https://doi.org/10.5012/bkcs.2007.28.11.2029

Abstract | Full Text: PDF


2034  

Efficient Hydrogenation Catalysts of Ni or Pd on Nanoporous Carbon Workable in an Acidic Condition
Donghwan Lee, Honggon Kim, Min Kang, Ji Man Kim, Ik-Mo Lee*
Keywords: Hydrogenation catalysts, Ni, Pd, Nanoporous carbon, Trifluoroacetic acid
DOI: https://doi.org/10.5012/bkcs.2007.28.11.2034

Abstract | Full Text: PDF


2041  

Endo- and Exo-Coordinated Mercury(II) Complexes of O3S2 Macrocycles:
Effect of Dibenzo-Substituents on Coordination Mode
Ji-Eun Lee, Hyun Jee Kim, So Young Lee, Jai Young Lee, Yongnu Jin, Shim Sung Lee*
Keywords: O3S2-Donor macrocycles, Dibenzo-substituents, Mercury(II) complex, Exo- and endo-coordinations
DOI: https://doi.org/10.5012/bkcs.2007.28.11.2041

Abstract | Full Text: PDF


2045  

Cyclometalated Platinum(II) Complexes Derived from a Chiral Pyridine Ligand: Synthesis, Structure, and Catalytic Activity
Myeong Sik Yoon, Dowook Ryu, Jeongryul Kim, Rengan Ramesh, Kyo Han Ahn*
Keywords: Chiral ligand, Cycloplatination, X-ray structure, C-H···Cl hydrogen bonding, Asymmetric reactions
DOI: https://doi.org/10.5012/bkcs.2007.28.11.2045

Abstract | Full Text: PDF


2051  

Solvent Effect on Sulfur Ylide Mediated Epoxidation Reaction
Hee-Yoon Lee*, Imhyuck Bae, Kyung-Hyun Min
Keywords: Sulfur ylide, Epoxidation, Solvent effect, Stereoselectivity
DOI: https://doi.org/10.5012/bkcs.2007.28.11.2051

Abstract | Full Text: PDF


2056  

A Synthesis of High Purity Single-Walled Carbon Nanotubes from Small Diameters of Cobalt Nanoparticles by Using Oxygen-Assisted Chemical Vapor Deposition Process
Hye Ryung Byon, Hyunseob Lim, Hyun Jae Song, Hee Cheul Choi*
Keywords: Cobalt nanoparticle, Oxygen-assisted chemical vapor deposition, Single-walled carbon nanotubes.
DOI: https://doi.org/10.5012/bkcs.2007.28.11.2056

Abstract | Full Text: PDF


2061  

First Concise Synthesis of Biologically Interesting Nigrolineabenzopyran A,(±)-Blandachromene II, and (±)-Daurichromene D
Yong Rok Lee*, Xue Wang
Keywords: Benzopyran, Nigrolineabenzopyran A, Blandachromene II, Daurichromene D
DOI: https://doi.org/10.5012/bkcs.2007.28.11.2061

Abstract | Full Text: PDF


2065  

Nanoscale Morphology of Bis(1-anthraquinoxy)glycols
Soon-Sik Kwon, Hui Liang, Jong Pil Kim, Young-A Lee, Ok-Sang Jung*
Keywords: 1-Anthraquinone substitutes, Morphology, Nanobelts, Nanowires, π-π interaction
DOI: https://doi.org/10.5012/bkcs.2007.28.11.2065

Abstract | Full Text: PDF


2069  

Simulation of 27Al MQMAS NMR Spectra of Mordenites Using Point Charge Model with First Layer Only and Multiple Layers of Atoms
Seen Ae Chae, Oc Hee Han*, Sang Yeon Lee
Keywords: 27Al MQMAS, Solid-state NMR, Mordenite, Point charge model, Si/Al ratio
DOI: https://doi.org/10.5012/bkcs.2007.28.11.2069

Abstract | Full Text: PDF


2075  

Trimerization of Isobutene over Solid Acid Catalysts under Wide Reaction Conditions
Ji Woong Yoon, Sung Hwa Jhung*, Tae-Jin Kim, Hee-Du Lee, Nak Han Jang, Jong-San Chang*
Keywords: Isobutene, Trimerization, Space velocity, Acid concentration, Cation exchange resin
DOI: https://doi.org/10.5012/bkcs.2007.28.11.2075

Abstract | Full Text: PDF


2079  

Fabrication and Optical Characterization of Rugate-structured Polymer Replicas
Jihoon Kim, Cheolyoung Park, Sung Jin Kim, Jaehyun Park, Young Chun Ko*, Hee-Gweon Woo,Honglae Sohn*
Keywords: Rugate filter, Porous silicon, Photonic structure, Polymer replica
DOI: https://doi.org/10.5012/bkcs.2007.28.11.2079

Abstract | Full Text: PDF


2083  

Detection of Avidin Based on Rugate-structured Porous Silicon Interferometer
Youngdae Koh, Sung Jin Kim, Jaehyun Park, Cheolyoung Park, Sungdong Cho, Hee-Gweon Woo, Young Chun Ko*, Honglae Sohn*
Keywords: Rugate structure, Porous silicon, Biotin, Avidin
DOI: https://doi.org/10.5012/bkcs.2007.28.11.2083

Abstract | Full Text: PDF


2089  

Visible Light Driven ZnFe2Ta2O9 Catalyzed Decomposition of H2S for Solar Hydrogen Production
Esakkiappan Subramanian, Jin-Ook Baeg*, Bharat B. Kale, Sang Mi Lee, Sang-Jin Moon, Ki-jeong Kong
Keywords: ZnFe2Ta2O9, Photocatalyst, H2S decomposition, Solar hydrogen
DOI: https://doi.org/10.5012/bkcs.2007.28.11.2089

Abstract | Full Text: PDF


2093  

Eschenmoser-Claisen Rearrangement of Baylis-Hillman Adducts
Jeong Mi Kim, Sung Hwan Kim, Jae Nyoung Kim*
Keywords: Eschenmoser-Claisen rearrangement, Baylis-Hillman adducts, DMA-DMA
DOI: https://doi.org/10.5012/bkcs.2007.28.11.2093

Abstract | Full Text: PDF


2096  

(S)-Selective Dynamic Kinetic Resolution of Allylic Alcohols by Enzyme-Metal Bicatalysis
Mahn-Joo Kim*, Han Ki Lee, Jaiwook Park*
Keywords: Dynamic kinetic resolution, Allylic alcohol, Subtilisin, Ruthenium, Enzyme-metal combination
DOI: https://doi.org/10.5012/bkcs.2007.28.11.2096

Abstract | Full Text: PDF


2099  

Incorporation of Fluorene-containing Pyridyl Ligand into Discrete Supramolecules via Coordination-Driven Self-Assembly
Mi-Eun Moon, Joo-Yeon Park, Hwan Kyu Kim, Ki-Whan Chi*
Keywords: Fluorine-containing pyridyl ligand, Coordination-driven self-assembly, Discrete supramolecules
DOI: https://doi.org/10.5012/bkcs.2007.28.11.2099

Abstract | Full Text: PDF


2103  

Preparation of Binaphthyldiamine Derived Chiral Stationary Phases
Jae Jeong Ryoo, Daniel W. Armstrong*
Keywords: Binaphthyldiamine, Chiral stationary phases, 2,2,2-Trifluoro-1-(9-anthryl)ethanol
DOI: https://doi.org/10.5012/bkcs.2007.28.11.2103

Abstract | Full Text: PDF


2107  

ICT-based Alkynylpyrene
Yeon Ok Lee, Hyo Sung Jung, Joung Hae Lee, Kwanghyun No*, Jong Seung Kim*
Keywords: Alkynylpyrene, ICT, Solvatochromic study, Protonation, Blue shift
DOI: https://doi.org/10.5012/bkcs.2007.28.11.2107

Abstract | Full Text: PDF