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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 28, Number 8
BKCSDE 28(8)
August 20, 2007 

 

1249  

Energy Transfer Pathway in Luminescent Lanthanide Complexes Based on Dansyl-N-methylaminobenzoic Acid through Intramolecular Charge Transfer State for Near Infrared Emission
Soo-Gyun Roh, Nam Seob Baek, Yong Hee Kim*, Hwan Kyu Kim*
Keywords: Luminescent lanthanide complexes, Dansyl-N-methylaminobenzoic acid, Energy transfer, Intramolecular charge transfer, Time-resolved luminescence
DOI: https://doi.org/10.5012/bkcs.2007.28.8.1249

Abstract | Full Text: PDF


1256  

Sensitized Near IR Luminescence of Er(III) Ion in Lanthanide Complexes Based on Diketone Derivatives: Synthesis and Photophysical Behaviors
Nam Seob Baek, Bong Kyu Kwak, Yong Hee Kim*, Hwan Kyu Kim*
Keywords: Lanthanide(III)-cored complexes, Energy transfer pathway, Triplet state, Near infrared (NIR) emission
DOI: https://doi.org/10.5012/bkcs.2007.28.8.1256

Abstract | Full Text: PDF


1261  

Isoetin 5'-Methyl Ether, A Cytotoxic Flavone from Trichosanthes kirilowii
Md. Aziz Abdur Rahman, Surk-Sik Moon*
Keywords: Trichosanthes kirilowii, Isoetin 5'-methyl ether, Tricin, Cytotoxicity
DOI: https://doi.org/10.5012/bkcs.2007.28.8.1261

Abstract | Full Text: PDF


1265  

Physicochemical and Catalytic Properties of NiSO4/CeO2-ZrO2 Catalyst Promoted with CeO2 for Acid Catalysis
Jong Rack Sohn*, Dong Cheol Shin
Keywords: NiSO4/CeO2-ZrO2, Acidity, CeO2-promoting, Cumene dealkylation, 2-Propanol dehydration
DOI: https://doi.org/10.5012/bkcs.2007.28.8.1265

Abstract | Full Text: PDF


1273  

Characterization of NiSO4 Supported on Fe2O3 and Catalytic Properties for Ethylene Dimerization
Young Il Pae, Jong Rack Sohn*
Keywords: NiSO4/Fe2O3 catalyst, Phase transition of Fe2O3, Acidic properties, Ethylene dimerization
DOI: https://doi.org/10.5012/bkcs.2007.28.8.1273

Abstract | Full Text: PDF


1280  

Preparation, Characterization and Photoluminescence Properties of Ca1-xSrxS:Eu Red-emitting Phosphors for a White LED
Hye-Jin Sung, Young-Sik Cho, Young-Duk Huh*, Young Rag Do
Keywords: Ca1-xSrxS:Eu phosphor, Three-band white LED, Photoluminescence
DOI: https://doi.org/10.5012/bkcs.2007.28.8.1280

Abstract | Full Text: PDF


1285  

Simultaneous Control of Au Nanotube Lengths and Pore Sizes with a Single Kind of Polycarbonate Membrane via Interfacial Deposition at the Air/Water Interface
Myoungho Pyo*, Jungsook Joo, Youn Su Jung
Keywords: PC membrane, Au nanotube, Electroless deposition, Interfacial deposition
DOI: https://doi.org/10.5012/bkcs.2007.28.8.1285

Abstract | Full Text: PDF


1289  

Isolation and Characterization of a New Alkaloid from the Seed of Prunus persica L. and Its Anti-inflammatory Activity
Jung-Rae Rho, Chang-Soo Jun, Young-Ae Ha, Myung-Ja Yoo, Ming-Xun Cui, Hwa-Seung Baek, Jin-A Lim, Young-Haeng Lee, Kyu-Yun Chai*
Keywords: Persicaside, Nitric oxide, Prostaglandin E2, Inducible nitric oxide synthase, Cyclooxygenase-2
DOI: https://doi.org/10.5012/bkcs.2007.28.8.1289

Abstract | Full Text: PDF


1294  

Identification of New Compounds from Catharanthus roseus Hairy Root Cultures
Ill-Min Chung, Mohd Ali, Young-Mok Yang, Christie A. M. Peebles, Se-Chul Chun, Sun-Joo Lee, Ka-Yiu San*, Ateeque Ahmad*
Keywords: Catharanthus roseus, Apocynaceae, Cultures hairy roots, New constituents.
DOI: https://doi.org/10.5012/bkcs.2007.28.8.1294

Abstract | Full Text: PDF


1299  

Preparation and Characterization of Half-Sandwich Cobalt(III) Complexes of Cp Ligands with a Rigid Thioanisole Side-Chain
Sujith S, Bun Yeoul Lee*, Jin Wook Han*
Keywords: Cyclopentadienyl, Cobalt(III) complex, X-ray structure
DOI: https://doi.org/10.5012/bkcs.2007.28.8.1299

Abstract | Full Text: PDF


1305  

Cyclopolymerization of 1,1-Dipropargyl-1-silacyclohexane by Transition Metal Catalysts
Yeong-Soon Gal, In-Sook Lee, Eun-Hee Chang, Yun-Cheol Jeong, Young-Woo Kwak*
Keywords: Cyclopolymerization, Catalysts, Conjugated spirocyclic polymer, Polyacetylenes, Silacyclohexane
DOI: https://doi.org/10.5012/bkcs.2007.28.8.1305

Abstract | Full Text: PDF


1311  

Synthesis and Application of New Ru(II) Complexes for Dye-Sensitized Nanocrystalline TiO2 Solar Cells
Won K. Seok*, A. K. Gupta, Seung-Jae Roh, Wonjoo Lee, Sung-Hwan Han*
Keywords: DSCs, New photosensitizers, Chromophore
DOI: https://doi.org/10.5012/bkcs.2007.28.8.1311

Abstract | Full Text: PDF


1317  

Synthesis and Characterization of a Hydroxylated Dendrimeric Gene Delivery Carrier
Tae-il Kim, Cheng Zhe Bai, Jong-sang Park*
Keywords: Hydroxylation, Propylene oxide, Dendrimer, Gene delivery
DOI: https://doi.org/10.5012/bkcs.2007.28.8.1317

Abstract | Full Text: PDF


1322  

Electrocatalysis of Oxygen Reduction by Cu-containing Polymer Films on Glassy Carbon Electrodes
Jongwon Kim*, Andrew A. Gewirth
Keywords: Copper-containing polymer, Electrocatalysis, Oxygen reduction, Cyclic voltammetry, Rotating disk electrode
DOI: https://doi.org/10.5012/bkcs.2007.28.8.1322

Abstract | Full Text: PDF


1329  

Electro-oxidation Kinetics of Cerium(III) in Nitric Acid Using Divided Electrochemical Cell for Application in the Mediated Electrochemical Oxidation of Phenol
Manickam Matheswaran, Subramanian Balaji, Sang Joon Chung, Il Shik Moon*
Keywords: Direct electrochemical oxidation, Mediated electrochemical oxidation, Cerium, Nitric acid, Phenol
DOI: https://doi.org/10.5012/bkcs.2007.28.8.1329

Abstract | Full Text: PDF


1335  

Homology Modeling and Docking Study of β-Ketoacyl Acyl Carrier Protein Synthase III from Enterococcus Faecalis
Ki-Woong Jeong, Jee-Young Lee, Yangmee Kim*
Keywords: KAS III, Enterococcus faecalis, Fatty acid synthesis, Antibiotics, Flavonoids
DOI: https://doi.org/10.5012/bkcs.2007.28.8.1335

Abstract | Full Text: PDF


1341  

The Effects of Ar-ion Bombardment and Annealing of D2O/Zircaloy-4 Surfaces Using XPS and UPS
Kyung-Sun Oh, Yong-Cheol Kang*
Keywords: Zircaloy-4, D2O, X-ray photoelectron spectroscopy, UV Photoelectron spectroscopy
DOI: https://doi.org/10.5012/bkcs.2007.28.8.1341

Abstract | Full Text: PDF


1346  

A Kinetic Consideration on the Selective Adsorption and Molecular Recognition by Molecularly Imprinted Polymer
Wuke Li, Songjun Li*, Gang Luo, Kerong Ding
Keywords: Molecularly imprinted polymer, Adsorption, Kinetics
DOI: https://doi.org/10.5012/bkcs.2007.28.8.1346

Abstract | Full Text: PDF


1353  

Aminolyses of Y-substituted Phenyl 2-Furoates and Cinnamates: Effect of Nonleaving Group Substituent on Reactivity and Mechanism
Ik-Hwan Um*, Kalsoom Akhtar, Youn-Min Park, Sher Bahadar Khan
Keywords: Aminolysis, Brønsted-type plot, Rate-determining step, Concerted mechanism, Stepwise mechanism.
DOI: https://doi.org/10.5012/bkcs.2007.28.8.1353

Abstract | Full Text: PDF


1358  

Ab initio Studies on Acene Tetramers: Herringbone Structure
Young Hee Park, Kiyull Yang*, Yun-Hi Kim, Soon Ki Kwon
Keywords: Organic thin-film transistor (OTFT), Hole/electron transfer rate, π-π interaction, Transfer integral, Binding energy of acene tetramer
DOI: https://doi.org/10.5012/bkcs.2007.28.8.1358

Abstract | Full Text: PDF


1363  

Characteristic Effects of 4,5-Disubstituted Pyridazin-3-one Derivatives with Various Functional Groups: Ab initio Study
Yong-Jin Yoon, In-Sun Koo, Jong Keun Park*
Keywords: Geometrical structure, Bond length, Atomic charge, Electron donating/withdrawing group, Binding energy
DOI: https://doi.org/10.5012/bkcs.2007.28.8.1363

Abstract | Full Text: PDF


1371  

Molecular Dynamics Simulation Study of the Transport Properties of Liquid Argon: The Green-Kubo Formula Revisited
Song Hi Lee
Keywords: Diffusion, Shear viscosity, Thermal conductivity, Liquid argon, Molecular dynamics simulation
DOI: https://doi.org/10.5012/bkcs.2007.28.8.1371

Abstract | Full Text: PDF


1375  

Determination of Cadmium(II) and Copper(II) by Flame Atomic Absorption Spectrometry after Preconcentration on Column with Pulverized Amberlite XAD-4 with Bismuthiol I
Dong Seok Park, Hee-Seon Choi*
Keywords: Cadmium(II), Copper(II), Adsorption, Amberlite XAD-4, Bismuthiol I (BI)
DOI: https://doi.org/10.5012/bkcs.2007.28.8.1375

Abstract | Full Text: PDF


1383  

Evaluation Method on Destruction and Removal Efficiency of Perfluorocompounds from Semiconductor and Display Manufacturing
Jee-Yon Lee, Jin Bok Lee, Dong Min Moon, Jun Hyung Souk, Seung Yeon Lee, Jin Seog Kim*
Keywords: PFC, Destruction and removal efficiency (DRE), Scrubber efficiency, Global warming, Gas mass spectrometer.
DOI: https://doi.org/10.5012/bkcs.2007.28.8.1383

Abstract | Full Text: PDF


1389  

Synthesis, Photophysical and Electrochemical Properties of Novel Conjugated Donor-Acceptor Molecules Based on Phenothiazine and Benzimidazole
Xiao-Hang Zhang, Seon Ho Kim, In Su Lee, Chun Ji Gao, Sung Ik Yang*, Kwang-Hyun Ahn*
Keywords: Phenothiazine, Benzimidazole, Charge transfer, Donor-acceptor, Fluorophore
DOI: https://doi.org/10.5012/bkcs.2007.28.8.1389

Abstract | Full Text: PDF


1396  

Sebum Absorption Characteristics of Polymer Microgel-containing Face Powder
Young Keun Lee, Fan-Long Jin, Soo-Jin Park*
Keywords: Microgels, Sebum absorption ratio, Adhesiveness, Smoothness, Skin reaction
DOI: https://doi.org/10.5012/bkcs.2007.28.8.1396

Abstract | Full Text: PDF


1401  

Synthesis of Calycotomine via Pictet-Spengler Type Reaction of N,O-Acetal TMS Ethers as N-Acyliminium Ion Equivalents
Jung-Eun Yang, Jin-Kyung In, Mi-Sung Lee, Jae-Hwan Kwak, Heesoon Lee, Soo Jae Lee, Han-Young Kang, Young-Ger Suh*, Jae-Kyung Jung*
Keywords: Tetrahydroisoquinoline, Pictet-Spengler reaction, N,O-Acetal TMS ether, Alkaloid
DOI: https://doi.org/10.5012/bkcs.2007.28.8.1401

Abstract | Full Text: PDF


1405  

Electric Field-induced Charge Transfer of (Bu4N)2[Ru(dcbpyH)2-(NCS)2]
on Gold, Silver, and Copper Electrode Surfaces
Investigated by Means of Surface-enhanced Raman Scattering
Sang-Woo Joo
Keywords: Adsorption, (Bu4N)2[Ru(dcbpyH)2-(NCS)2] (N719), Potential-dependent SERS
DOI: https://doi.org/10.5012/bkcs.2007.28.8.1405

Abstract | Full Text: PDF


1410  

Determination of the Rate Constants for Bimolecular Reactions of O(3P) Atom with SiH4 and SiHCl3
Jee-Yon Lee, Hee-Soo Yoo*, Jin Seog Kim
Keywords: SiH4, SiHCl3, O(3P), Chemiluminescence imaging, Rate constant
DOI: https://doi.org/10.5012/bkcs.2007.28.8.1410

Abstract | Full Text: PDF


1413  

Binding Study of Naringenin Derivatives and Cyclin Dependent Kinase 2
Hojung Kim, Eunjung Lee, Jihye Kim, Jinyoung Kim, Haeyoung Lim, Chul-Hoon Lee, Joong-Hoon Ahn, Youhoon Chong, Yoongho Lim*
Keywords: Cyclin dependent kinase 2, Naringenin, NMR, in silico
DOI: https://doi.org/10.5012/bkcs.2007.28.8.1413

Abstract | Full Text: PDF


1416  

Synthesis and Structure of a Cadmium Selenite-Sulfate Cd4(SeO3)2(SO4)2
Yiming Xie*Jihuai Wu
Keywords: Cadmium, Crystal structure, Selenite, Sulfate
DOI: https://doi.org/10.5012/bkcs.2007.28.8.1416

Abstract | Full Text: PDF


1419  

An NMR Chiral Solvating Agent for the Chiral Recognition of the Two Enantiomers of N-(3,5-Dinitrobenzoyl)-α-amino Acids
Myung Ho Hyun*, Seung Nam Kim, Hee Jung Choi, Pachagounder Sakthivel
Keywords: Chiral recognition, NMR chiral solvating agent, N-(3,5-Dinitrobenzoyl)-α-amino acids, trans-1,2-Diaminocyclohexane
DOI: https://doi.org/10.5012/bkcs.2007.28.8.1419

Abstract | Full Text: PDF


1422  

A Practical and Simple Method of Recycling Catalyst in Asymmetric Aminohydroxylation of Olefins
Xiao Li Sun, Ying Jin, Wei He, Peng Juan Nan, Sheng Yong Zhang*
Keywords: Monomeric cinchona alkaloid ligand, Asymmetric aminohydroxylation, Recycle, Chiral β-aminoalcohol
DOI: https://doi.org/10.5012/bkcs.2007.28.8.1422

Abstract | Full Text: PDF


1425  

Existence of Critical Aggregation Concentration at the Very Dilute Regime of Poly(vinylidene fluoride)/Propylene Carbonate System
Il Hyun Park*, Zhi Yang Xu, Yun Ling, Bong Soo Kim, Jang Oo Lee
Keywords: Poly(vinylidene fluoride), Critical aggregation solution, Core-shell, Light scattering
DOI: https://doi.org/10.5012/bkcs.2007.28.8.1425

Abstract | Full Text: PDF


1429  

Weak Forces in Inorganic Lattices: Anion Roles in Lattice Assembly
Young Hoon Lee, Yu Chul Park*, Jack M. Harrowfield, Pierre Thuery, Yang Kim*
Keywords: Macrocycle, Dipicolinate, Crystal structure
DOI: https://doi.org/10.5012/bkcs.2007.28.8.1429

Abstract | Full Text: PDF


1433  

Preparation of Novel Nonlinear Optical Polyester with Enhanced Thermal Stability of Dipole Alignment
Ju-Yeon Lee*, Jin-Hyang Kim, Dong-Seon Won, Han-Na Jang
Keywords: Nonlinear optics, Polyester, Thermal stability, Second harmonic generation, Relaxation of dipole alignment
DOI: https://doi.org/10.5012/bkcs.2007.28.8.1433

Abstract | Full Text: PDF


1437  

Direct Formation of Silver Cluster Ions from Silver Salts by Laser Desorption/Ionization
Sung-Seen Choi*, Sung-Ho Ha, Hye Min Lee, Jong-Chul Kim
Keywords: Silver cluster, Silver salt, Desorption, Ionization, LDI-TOFMS
DOI: https://doi.org/10.5012/bkcs.2007.28.8.1437

Abstract | Full Text: PDF


1440  

Molecular Engineering. Part 14. Self-Assembled Oligovelcraplexes by π-π Stacking Interaction and Metal Coordination
Min-Jung KwakKyungsoo Paek*
Keywords: Molecular engineering, Oligovelcraplex, π-π stacking
DOI: https://doi.org/10.5012/bkcs.2007.28.8.1440

Abstract | Full Text: PDF