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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 30, Number 4
BKCSDE 30(4)
April 20, 2009 

 

771  

A Facile Total Synthesis of (-)-Frontalin, (-)-endo-Brevicomin and
(-)-exo-Brevicomin through PtCl4 Catalyzed Hydroalkoxylation Reaction
Hee Yoon Lee*, Yongsik Jung, Hyunsik Moon
Keywords: Precious metal catalysis, Hydroalkoxylation of alkyne, Asymmetric synthesis, Frontalin, Brevicomin
DOI: https://doi.org/10.5012/bkcs.2009.30.4.771

Abstract | Full Text: PDF


773  

Stereoselective Cylization of Allenoates Containing Carbonyl Functionalities
Mediated Mo(CO)6: Synthesis of Canadensolide and Sporothriolide
Jisook Kwon, Suyeon Gong, Seok Hoon Woo, Chan Mo Yu*
Keywords: Allenoate, Cyclocarbonylation, Diastereoselectivity, Lactone, Molybdenum
DOI: https://doi.org/10.5012/bkcs.2009.30.4.773

Abstract | Full Text: PDF


775  

Transient Photoelectron Spectrum of NaI During Photodissociation at 307 nm
Hyuk Kang
Keywords: NaI, Sodium iodide, Femtosecond real-time dynamics, Dissociation dynamics, Photoelectron spectrum
DOI: https://doi.org/10.5012/bkcs.2009.30.4.775

Abstract | Full Text: PDF


777  

Characterization of a Naturally Occurring Mutation (Ile-12 to Thr) Close to Prosthetic Group FAD in Human Dihydrolipoamide Dehydrogenase
Lin Yuan, Young Joon Cho, Hakjung Kim*
Keywords: Dihydrolipoamide dehydrogenase, Pyridine nucleotide-disulfide oxidoreductase, Site-directed mutagenesis, Dihydrolipoamide deficiency, α-Keto acid dehydrogenase complexes
DOI: https://doi.org/10.5012/bkcs.2009.30.4.777

Abstract | Full Text: PDF


779  

Discovery of Highly Potent Multidrug Resistance (MDR) Reversal Agents: Aminosulfonylaryl Isoxazole Derivatives
Young Taek Han, Eun Kyung Kim, Eun Ae Kim, Eun Seon Kim, Dae Kyong Kim, Young Ger Suh, Kyung Hoon Min*
Keywords: Multidrug resistance, P-glycoprotein, Isoxazole, MES-SA/DX5
DOI: https://doi.org/10.5012/bkcs.2009.30.4.779

Abstract | Full Text: PDF


781  

Anti-inflammatory Activity of N-Naphthoyl D-Alanine in vivo
Michimasa Goto*, Hiromi Kataoka, Yoshie Araya, Masashi Kawasaki, Kin ichi Oyama, Masanori Semma, Yoshio Ito, Atsushi Ichikawa
Keywords: D-Alanine, Anti-inflammatory activity, Zigzag structure, Carrageenan, COXs
DOI: https://doi.org/10.5012/bkcs.2009.30.4.781

Abstract | Full Text: PDF


783  

Thermal Behavior of LixCoO2 Cathode and Disruption of
Solid Electrolyte Interphase Film
Chil Hoon Doh*, Dong Hun Kim, Jung Hun Lee, Duck Jun Lee, Bong Soo Jin, Hyun Soo Kim, Seong In Moon, Younggi Hwang, Angathevar Veluchamy*
Keywords: Cathode, LixCoO2, Thermal analysis, Thermal stability, Solid electrolyte film
DOI: https://doi.org/10.5012/bkcs.2009.30.4.783

Abstract | Full Text: PDF


787  

Prediction of Hydroxyl Substitution Site(s) of Phenol, Monochlorophenols and 4-Chloronitrobenzene by Atomic Charge Distribution Calculations
Byung Dae Lee, Min Joo Lee*
Keywords: Atomic charge distribution, CHelpG, MK, Hydroxyl radical reaction
DOI: https://doi.org/10.5012/bkcs.2009.30.4.787

Abstract | Full Text: PDF


791  

Effects of Overexpression of C5 Protein on rnpB Gene Expression in Escherichia coli
Yool Kim, Younghoon Lee*
Keywords: M1 RNA, C5 Protein, RNase P, Coordinate regulation
DOI: https://doi.org/10.5012/bkcs.2009.30.4.791

Abstract | Full Text: PDF


794  

Effect of Basis Set Superposition Error on the MP2 Relative Energies of Gold Cluster Au6
Kyoung Hoon Kim, Jong Chan Kim, Young Kyu Han*
Keywords: Gold clusters, Density functional calculation, Coupled-cluster calculation, Basis set superposition error, Effective core potential
DOI: https://doi.org/10.5012/bkcs.2009.30.4.794

Abstract | Full Text: PDF


797  

Acetate-Promoted Aldol-Type Reaction: Scope and Reactivity of Acetates and Aldehydes
Dong Hyeon Kim, A F M Motiur Rahman, Byeong Seon Jeong, Eung Seok Lee, Yurngdong Jahng*
Keywords: Ammonium acetate, Aldol, 2,5-Bis-benzylidenecyclopentanone, 2,6-Bis-benzylidenecyclohexanone, Mackinazolinone
DOI: https://doi.org/10.5012/bkcs.2009.30.4.797

Abstract | Full Text: PDF


803  

Variation in IR and Raman Spectra of CD3CN upon Solvation of InCl3 in CD3CN:
Distinctive Blue Shifts, Coordination Number,
Donor-Acceptor Interaction, and Solvated Species
Jun Sung Cho, Han Gook Cho*
Keywords: Acetonitrile-d, InCl3, Coordination, Frequency shift, Solvation number
DOI: https://doi.org/10.5012/bkcs.2009.30.4.803

Abstract | Full Text: PDF


810  

Adsorption Properties of Keggin-type Polyoxometalates on Carbon Based Electrode Surfaces and Their Electrocatalytic Activities
Suhee Choi, Jongwon Kim*
Keywords: Polyoxometalate, Glassy carbon, Highly oriented pyrolytic graphite, Adsorption, Electrocatalysis
DOI: https://doi.org/10.5012/bkcs.2009.30.4.810

Abstract | Full Text: PDF


817  

A Novel Hybrid Supercapacitor Using a Graphite Cathode and a Niobium(V) Oxide Anode
Gum Jae Park, D Kalpana, Arjun Kumar Thapa, Hiroyoshi Nakamura, Yun Sung Lee*, Masaki Yoshio*
Keywords: Novel energy storage system, Graphite, Niobium(V) oxide, Intercalation/de-intercalation
DOI: https://doi.org/10.5012/bkcs.2009.30.4.817

Abstract | Full Text: PDF


821  

Effect of Lecithin on Dermal Safety of Nanoemulsion Prepared from Hydrogenated Lecithin and Silicone Oil
Duck Hwan Bae, Jae Sup Shin, Gwi Su Shin, Fan Long Jin, Soo Jin Park*
Keywords: Lecithin, Nanoemulsion, Interfacial tension, Zeta-potential, Skin safety
DOI: https://doi.org/10.5012/bkcs.2009.30.4.821

Abstract | Full Text: PDF


825  

Alum Catalyzed Simple and Efficient Synthesis of Bis(indolyl)methanes by Ultrasound Approach
Swapnil S Sonar, Sandip A Sadaphal, Amol H Kategaonkar, Rajkumar U Pokalwar, Bapurao B Shingate, Murlidhar S Shingare*
Keywords: Bis(indolyl)methanes, Alum, 1H-indole, Aldehydes/ketones, Ultrasound irradiation
DOI: https://doi.org/10.5012/bkcs.2009.30.4.825

Abstract | Full Text: PDF


829  

Enantioselective Fluorination of β-Keto Phosphonates and β-Ketoesters Catalyzed by Chiral Palladium Complexes
Na Ri Lee, Sun Mi Kim, Dae Young Kim*
Keywords: Chiral palladium complexes, Electrophilic fluorination, Asymmetric catalysis, β-Keto phosphonates, β-Ketoesters
DOI: https://doi.org/10.5012/bkcs.2009.30.4.829

Abstract | Full Text: PDF


837  

DFT Conformational Study of Calix[6]arene: Hydrogen Bond
Kwangho Kim, Jong In Choe*
Keywords: DFT, MPW1PW91, Calix[6]arene, Conformer, Hydrogen bond
DOI: https://doi.org/10.5012/bkcs.2009.30.4.837

Abstract | Full Text: PDF


846  

Synthesis and Structure Analysis of α and β Forms of
[12] Metallacrown-6 Nickel(II) Complex: [Ni6(SCH2CH2CH3)12]
Hai Lian Xiao, Fang Fang Jian*, Ke Jie Zhang
Keywords: Polymorphism, Nickel cluster compounds, Crown compounds, Crystal structure
DOI: https://doi.org/10.5012/bkcs.2009.30.4.846

Abstract | Full Text: PDF


849  

Determination of Correlation Times of New Paramagnetic Gadolinium MR Contrast Agents by EPR and 17O NMR
Hee Kyung Kim, Gang Ho Lee, Tae Jeong Kim*, Yongmin Chang*
Keywords: MRI CA, Gadolinium chelate, Tranexamate, Correlation times
DOI: https://doi.org/10.5012/bkcs.2009.30.4.849

Abstract | Full Text: PDF


853  

Deposition of CuInSe2 Thin Films Using Stable Copper and Indium-selenide Precursors through Two-stage MOCVD Method
Jong Pil Park, Sin Kyu Kim, Jae Young Park, Kang Min Ok, Il Wun Shim*
Keywords: CuInSe2, CIS, Thin film, MOCVD, Solar cell
DOI: https://doi.org/10.5012/bkcs.2009.30.4.853

Abstract | Full Text: PDF


857  

Local Structure Invariant Potential for InxGa1-xAs Semiconductor Alloys
Eunji Sim*, Minwoo Han, Joost Beckers, Simon de Leeuw
Keywords: Alloys, Semiconductors, Empirical potential, Molecular dynamics simulation, Quantum well structures
DOI: https://doi.org/10.5012/bkcs.2009.30.4.857

Abstract | Full Text: PDF


863  

Electroluminescent Properties of Spiro[fluorene-benzofluorene]-Containing Blue Light Emitting Materials
Soon Ok Jeon, Hyun Seok Lee, Young Min Jeon, Joon Woo Kim, Chil Won Lee, Myoung Seon Gong*
Keywords: Blue OLED, Host, Dopant, Spiro[fluorene-benzofluorene], Color purity
DOI: https://doi.org/10.5012/bkcs.2009.30.4.863

Abstract | Full Text: PDF


869  

Fabrication of Double-Doped Magnetic Silica Nanospheres and Deposition of Thin Gold Layer
Sang Eun Park, Jea Won Lee, Seung Joo Haam, Sang Wha Lee*
Keywords: Double-doped, Magnetites, Gold, Silica, Nanoshell
DOI: https://doi.org/10.5012/bkcs.2009.30.4.869

Abstract | Full Text: PDF


873  

Preparation and Unequivocal Identification of Chromophores-Substituted Carbosilane Dendrimers up to 7th Generations
Chungkyun Kim*, Hyojung Kim, Myeong Jin Oh, Jang Hwan Hong
Keywords: Dendrimer, Silane, Siloxane, Photoluminescence, GPC
DOI: https://doi.org/10.5012/bkcs.2009.30.4.873

Abstract | Full Text: PDF


882  

Quantitative Determination of the Chromophore Alignment Induced by Electrode Contact Poling in Self-Assembled NLO Materials
Tae Dong Kim*, Jingdong Luo, Alex K Y Jen*
Keywords: Nonlinear optics, Chromophore, Self-assembly, Order parameter, Contact poling
DOI: https://doi.org/10.5012/bkcs.2009.30.4.882

Abstract | Full Text: PDF


887  

Regeneration of a Micro-Scratched Tooth Enamel Layer by Nanoscale Hydroxyapatite Solution
Su Chak Ryu, Byoung Ki Lim, Fangfang Sun, Kwangnak Koh, Dong Wook Han, Jaebeom Lee*
Keywords: Hydroxyapatite (HAp), Human tooth, Regeneration, Ca2+ ion, PO43- ion
DOI: https://doi.org/10.5012/bkcs.2009.30.4.887

Abstract | Full Text: PDF


891  

Decoupling of Background and Resonance Scatterings in Multichannel Quantum Defect Theory and Extraction of Dynamic Parameters from Lu-Fano Plot
Chun Woo Lee
Keywords: MQDT, Resonance, Background scattering, Phase renormalization
DOI: https://doi.org/10.5012/bkcs.2009.30.4.891

Abstract | Full Text: PDF


897  

Delivery of Hypoxia Inducible Heme Oxygenase-1 Gene Using Dexamethasone Conjugated Polyethylenimine for Protection of Cardiomyocytes under Hypoxia
Hyunjung Kim, Hyun Ah Kim, Joon Sig Choi, Minhyung Lee*
Keywords: Dexamethasone, Cardiomyocytes, Heme oxygenase-1, Hypoxia, Polyethylenimine
DOI: https://doi.org/10.5012/bkcs.2009.30.4.897

Abstract | Full Text: PDF


902  

Electrostatic Properties of N-Acetyl-Cysteine-Coated Gold Surfaces
Interacting with TiO2 Surfaces
Jin Won Park
Keywords: N-Acetyl cysteine, Gold surface, TiO2 surface, AFM, DLVO theory
DOI: https://doi.org/10.5012/bkcs.2009.30.4.902

Abstract | Full Text: PDF


907  

Spatial Symmetry Breaking in the Revival Wave of the Belousov-Zhabotinsky Reaction Containing 1,4-Cyclohexanedione
C Basavaraja, Na Ri Kim, Hyun Tae Park, Do Sung Huh*
Keywords: BZ-Reaction, Chaotic breakup, Divided-dish, Reaction-diffusion, Revival wave
DOI: https://doi.org/10.5012/bkcs.2009.30.4.907

Abstract | Full Text: PDF


913  

Rebinding Dynamics of CO Following Photodissociation of 4.0 M Guanidine HCl-Denatured Carbonmonoxyhemoglobin
Jaeheung Park, Taegon Lee, Jooyoung Kim, Salina A Chowdhurry, Manho Lim*
Keywords: CO rebinding, Hemoglobin, Guanidine HCl, Femtosecond vibrational spectroscopy, Denaturation
DOI: https://doi.org/10.5012/bkcs.2009.30.4.913

Abstract | Full Text: PDF


917  

A Substrate Serves as a Hydrogen Atom Donor in the Enzyme-Initiated Catalytic Mechanism of Dual Positional Specific Maize Lipoxygenase-1
Thavrak Huon, Sungkuk Jang, Kyoungwon Cho, Randeep Rakwal, Je Chang Woo, Ilchul Kim, Seung Wook Chi, Oksoo Han*
Keywords: Dual positional lipoxygenase, Enzyme-initiated mechanism, Kinetic control, Thermodynamic control, Radical mechanism
DOI: https://doi.org/10.5012/bkcs.2009.30.4.917

Abstract | Full Text: PDF


924  

NSC-87877 Inhibits Cdc25A and Cdc25B
Mina Song, Sayeon Cho*
Keywords: Cdc25, NSC-87877, PTP inhibitor
DOI: https://doi.org/10.5012/bkcs.2009.30.4.924

Abstract | Full Text: PDF


927  

Analysis of the Relationship between the Molecular Weight and Transfection Efficiency/Cytotoxicity of Poly-L-arginine on a Mammalian Cell Line
Heebeom Koo, Hyunseo Kang, Yan Lee*
Keywords: Cytotoxicity, Gene delivery, Polyarginine, Polylysine, Transfection
DOI: https://doi.org/10.5012/bkcs.2009.30.4.927

Abstract | Full Text: PDF


931  

Preparation of Naproxen-Loaded Poly(ethylene oxide-b-methacrylic acid) Micelle and Its pH-dependent Drug Release Behavior
Geun woo Jin, Xu Ying Ji, Joon Sig Choi
Keywords: Polymeric micelle, Naproxen, Poly(ethylene oxide), Poly(methacrylic acid)
DOI: https://doi.org/10.5012/bkcs.2009.30.4.931

Abstract | Full Text: PDF


935  

Synthesis of New Chiral Chromonic Lyotropic Liquid Crystal Based on Perylenebis(dicarboximide)
Jaishri J Naidu, Yun Ju Bae, Kwang Un Jeong, Seung Hee Lee, Shinwoong Kang,Myong Hoon Lee*
Keywords: Chiral lyotropic chromonic LCs, Cholesteric fingerprint texture, Chiral nematic (N*) phase
DOI: https://doi.org/10.5012/bkcs.2009.30.4.935

Abstract | Full Text: PDF


938  

Expedient Synthesis of 5-Benzoylpyrimidine-2,4-diones from Baylis-Hillman Adducts
Jeong Mi Kim, Eun Sun Kim, Jae Nyoung Kim*
Keywords: Baylis-Hillman adducts, Pyrimidine-2,4-diones, PCC oxidation
DOI: https://doi.org/10.5012/bkcs.2009.30.4.938

Abstract | Full Text: PDF


941  

Synthesis of Rearranged N-Tosyl Aza-Baylis-Hillman Adducts under Acidic Conditions Catalyzed by CH3SO3H or Montmorillonite K10
Hoo Sook Kim, Hyun Seung Lee, Jae Nyoung Kim*
Keywords: Methanesulfonic acid, Montmorillonite K10, Aza-Baylis-Hillman adducts
DOI: https://doi.org/10.5012/bkcs.2009.30.4.941

Abstract | Full Text: PDF


945  

An Important Application of Pirkle Type π-Acidic Chiral Stationary Phases: Resolution of Polynuclear Aromatic Hydrocarbon Mixtures by Normal-Phase Conventional and Capillary HPLC
Jae Jeong Ryoo
Keywords: PAH, Normal phase HPLC, Pirkle type π-acidic chiral stationary phase, Capillary HPLC
DOI: https://doi.org/10.5012/bkcs.2009.30.4.945

Abstract | Full Text: PDF


948  

Solvent-Induced Reversible Monolayer-Bilayer Transition in Self-Assembled Lamellar Cobalt(II) Dodecanesulfonate Hydrate
Seong Hun Park, Young Duk Huh*
Keywords: Solvent-induced phase transition, Organic-inorganic hybrids, Monolayer-bilayer transition
DOI: https://doi.org/10.5012/bkcs.2009.30.4.948

Abstract | Full Text: PDF


951  

A Thiophene, Benzothiadiazole, and Carbazole-Based Copolymer : Synthesis and Characterization
Ji Cheng Li, Qing Bo Meng, Jong Seok Kim, Youn Sik Lee*
Keywords: 3-Hexylthiophene, Benzothiadiazole, 2-Ethylhexylcarbazole, Low band gap, Photovoltaic device
DOI: https://doi.org/10.5012/bkcs.2009.30.4.951

Abstract | Full Text: PDF


955  

Electrochemically Directed Modification of ITO Electrodes and Its Feasibility for the Immunosensor Development
Daegeun Yu, Kyuwon Kim*
Keywords: Electrochemical modification, Indium-tin-oxide, Fluorescence, Immunosensor, Immunoassay
DOI: https://doi.org/10.5012/bkcs.2009.30.4.955

Abstract | Full Text: PDF


959  

Crystallization and Preliminary X-Ray Crystallographic Studies of Rattus norvegicus Visfatin/PBEF/Nampt in Complex with an FK866-Based Inhibitor
Mun Kyoung Kim, Man Ho Bae, Isak Im, Gil Bu Kang, Hye Eun Song, Yongseong Kim, Jang Soo Chun, Yong Chul Kim, Soo Hyun Eom*
Keywords: Crystallization, FK866, Nicotinamide phosphoribosyltransferase (Nampt), Pre-B-cell colony-enhancing factor (PBEF), Visfatin
DOI: https://doi.org/10.5012/bkcs.2009.30.4.959

Abstract | Full Text: PDF


961  

Mercury(II) Halide and Copper(I) Iodide Complexes of Double-Tweezer Ligand with Thiocyclohexyl End-Group
Jai Young Lee, Sanjina Lee, Minhye Jo, Hayan Lee, Ki Min Park, Shim Sung Lee*
Keywords: Double-tweezer ligand, Mercury(II) halide, Copper(I) iodide, Complex, Crystal structure
DOI: https://doi.org/10.5012/bkcs.2009.30.4.961

Abstract | Full Text: PDF


965  

Hydrothermal Synthesis and Crystal Structure of A Three-Dimensional
Open-Framework Tin(II) Phosphate, [H2DACO]0.52+[Sn4(PO4)3]-
Leqing Fan*, Jihuai Wu, Yunfang Huang, Jianming Lin
Keywords: Tin(II) phosphate, Hydrothermal synthesis, Open-framework, Crystal structure
DOI: https://doi.org/10.5012/bkcs.2009.30.4.965

Abstract | Full Text: PDF


969  

Synthesis of New Alkylene-Linked Donepezil-Aminothienoquinoline Hybrid Related Derivatives
Yang Heon Song*, Boung Sun Jo
Keywords: Acetylcholinesterase inhibitor, Donepezil, Aminothienoquinoline
DOI: https://doi.org/10.5012/bkcs.2009.30.4.969

Abstract | Full Text: PDF


972  

Oxidation of Hantzsch 1,4-Dihydropyridines Using Supported Nitric Acid on Silica Gel and Poly Vinyl Pyrrolidone (PVP) under Mild and Heterogeneous Conditions
Arash Ghorbani Choghamarani*, Mohsen Nikoorazm, Hamid Goudarziafshar, Lotfi Shiri, Zahra Chenani
Keywords: 1,4-Dihydropyridines, Oxidation, Poly vinyl pyrrolidone (PVP), Silica gel, Nitric acid
DOI: https://doi.org/10.5012/bkcs.2009.30.4.972

Abstract | Full Text: PDF


975  

Kinetics and Mechanism of the Aminolysis of Dimethyl Thiophosphinic Chloride with Anilines
Nilay Kumar Dey, Chan Kyung Kim*, Hai Whang Lee*
Keywords: Anilinolysis, Dimethyl thiophosphinic chloride, Steric effect, Deuterium kinetic isotope effect
DOI: https://doi.org/10.5012/bkcs.2009.30.4.975

Abstract | Full Text: PDF